Process for methylating aromatic hydrocarbons

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United States of America Patent

PATENT NO 10696608
APP PUB NO 20190218159A1
SERIAL NO

16336034

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Abstract

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In a process for producing paraxylene, a hydrocarbon feedstock comprising benzene and/or toluene is contacted with an alkylating reagent comprising methanol and/or dimethyl ether in an alkylation reaction zone under alkylation conditions in the presence of an alkylation catalyst to produce an alkylated product comprising xylenes. The alkylation catalyst comprises a molecular sieve having a Constraint Index ≤5, and the alkylation conditions comprise a temperature less than 500° C. At least part of the alkylated product is supplied to a paraxylene recovery unit to recover paraxylene and produce a paraxylene-depleted stream, which is then contacted with a xylene isomerization catalyst under conditions effective to isomerize xylenes in the paraxylene-depleted stream and produce an isomerized stream having a higher concentration of paraxylene than the paraxylene-depleted stream. At least part of the isomerized stream is then recycled to the paraxylene recovery unit to recover the paraxylene therein.

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Patent Owner(s)

Patent OwnerAddress
EXXONMOBIL CHEMICAL PATENTS INC5200 BAYWAY DRIVE BAYTOWN TX 77520

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Chen, Tan-Jen Seattle, US 85 969
Detjen, Todd E Houston, US 19 20
Loveless, Brett T Houston, US 13 30
Tinger, Robert G Friendswood, US 55 356

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