Butadiene telomerization catalyst and preparation thereof

Number of patents in Portfolio can not be more than 2000

United States of America

PATENT NO 11312670
APP PUB NO 20180072637A1
SERIAL NO

15564543

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Abstract

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Catalyst compositions are prepared by contacting a palladium source and 1,3,5,7-tetramethyl-6-(2,4-dimethoxyphenyl)-2,4,8-trioxa-6-phosphaadamantane and a methoxyocta-diene compound, in a primary aliphatic alcohol, under suitable conditions including a ratio of equivalents of palladium to equivalents of 1,3,5,7-tetramethyl-6-(2,4-dimethoxyphenyl)-2,4,8-trioxa-6-phosphaadamantane ranging from greater than 1:1 to 1:1.3. The result is a complex of palladium, a 1,3,5,7-tetramethyl-6-(2,4-dimethoxyphenyl)-2,4,8-trioxa-6-phosphaada-mantane ligand, and a ligand selected from a methoxyoctadiene ligand, an octadienyl ligand, or a protonated octadienyl. Such complexes may, in solution, exhibit surprising solubility and storage stability and are useful in the telomerization of butadiene, which is a step in the production of 1-octene.

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Patent Owner(s)

Patent OwnerAddress
DOW GLOBAL TECHNOLOGIES LLC2211 H H DOW WAY MIDLAND MI 48674

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Briggs, John R Midland, US 40 368
Klinkenberg, Jessica L Midland, US 9 5

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