ELECTROPLATING OF METALS USING PULSED REVERSE CURRENT FOR CONTROL OF HYDROGEN EVOLUTION

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United States of America Patent

APP PUB NO 20010054557A1
SERIAL NO

08871599

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ATTORNEY / AGENT: (SPONSORED)

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Abstract

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Excessive evolution of hydrogen in electrolytic deposition of metals on a cathode substrate can be controlled by using a pulsed reverse current. Reverse current pulses interposed between the forward current pulses consume at least some of the nascent hydrogen and prevent the local pH at the cathode surface from becoming excessively alkaline. Control of hydroxide ion concentration by pulsed reverse current alleviates problems caused by reaction of metal-bearing-ions with hydroxide ions generated near the cathode by evolution of hydrogen. The method is useful in depositing functional chromium coatings on electrically conductive substrates from plating baths comprising aqueous solutions of trivalent chromium salts. In such a method the current comprises forward pulses having a duty cycle of from about 50% to about 90% and reverse pulses having a duty cycle of from about 5% to about 30%, and a frequency of from about 5 Hz to about 700 Hz.

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Patent Owner(s)

Patent OwnerAddress
FARADAY TECHNOLOGY INC315 HULS DRIVE ENGLEWOOD OH 45315

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
RENZ, ROBERT P CENTERVILLE, OH 6 75
STORTZ, ERIC C CLARENDON HILLS, IL 2 25
TAYLOR, E JENNINGS TROY, OH 46 717
ZHOU, CHENGDONG SALEM, OR 10 293

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