BONDED BODY OF GALVANIZED STEEL SHEET AND ADHEREND, AND MANUFACTURING METHOD THEREOF
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United States of America Patent
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Issued Date -
Jan 13, 2011
app pub date -
Mar 16, 2009
filing date -
Mar 17, 2008
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Abandoned
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Abstract
The invention is a technique for strongly integrating a galvanized steel sheet and a resin molded article. A hot-dip galvanized steel sheet “Z18” is immersed in an aqueous solution for aluminum degreasing at 75° C. for 7 minutes, to form roughness having an RSm of 0.8 to 2.3 μm and an Rz of 0.3 to 1.0 μm on the surface. The surface is covered with convex protrusions having a diameter of about 100 nm, and a chromate treatment layer appears in the surface. In other words, three conditions suitable for bonding are satisfied thereby. A resin composition comprising 70 to 97 wt % of polyphenylene sulfide and 3 to 30 wt % of a polyolefin resin is injected onto the surface. The resin composition penetrates into ultra-fine irregularities and is cured in that state, whereby a composite in which the galvanized steel sheet and the resin molded article are strongly integrated is obtained. The shear rupture strength of the composite is extremely high, in excess of 20 MPa.
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