SUPRAMOLECULAR COMPLEXES AS PHOTOCATALYSTS FOR REDUCTION
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United States of America Patent
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Issued Date -
Nov 13, 2014
app pub date -
Feb 6, 2014
filing date -
Mar 21, 2007
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Abandoned
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Abstract
Supramolecular complexes, methods and systems for photocatalysis of the reduction of substrates are described. The supramolecular complexes of the invention have a light absorbing metal center, an electron collector ligand and a catalytically active metal. When the supramolecular complexes are exposed to radiant energy, the light absorbing metal center creates a charge that is transferred to the electron collector ligand to form a charge transfer state. The charge is then transferred through the catalytically active metal to a substrate, cause the reduction of the substrate, e.g. the reduction of water to molecular hydrogen.
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