PROCESS FOR REMOVING MERCAPTANS FROM A GAS STREAM

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United States of America Patent

APP PUB NO 20160279566A1
SERIAL NO

15036130

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ATTORNEY / AGENT: (SPONSORED)

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Abstract

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The present invention relates to a process for removing mercaptans from a gas stream. First, a gas stream comprising at least a mercaptan of the general formula R1—SH, wherein R1 is an alkyl group comprising 1 to 4 carbon atoms, may be contacted with an absorption medium comprising a solvent, a substituted disulfide of the general formula R2—SS—R3 wherein R2 and R3 are carbon comprising substituents of which the corresponding R2—SH and R3—SH thiols have a vapour pressure below the vapour pressure of any R1—SH thiol and at least one of R2 and R3 is an electron withdrawing group; and at least a catalytic amount of a base. The absorption medium may be retrieved and regenerated in a regeneration unit. The regenerated absorption solution may be recycled and subjected to oxidation.

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Patent Owner(s)

Patent OwnerAddress
SHELL OIL COMPANYP O BOX 2463 910 LOUISIANA HOUSTON TX 77252-2463

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
SMITS, Jozef Jacobus Titus Amsterdam, NL 12 16
WADMAN, Sipke Hidde Amsterdam, NL 19 14

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