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Abstract

Processes for purifying and liquefying natural gas in conjunction and integration with cryogenic processing natural gas to recover natural gas liquids (NGL) is disclosed. In the process, the natural gas stream to be purified and liquefied is taken from top outlet stream of demethanizer in the cryogenic NGL recovery plant, first purified and then cooled under moderate pressure to condense it as a liquefied natural gas (LNG) product stream. Some of the cooling required for the demethanizer reflux stream is provided by natural gas liquefaction section before supplied to top of the column to serve as reflux. The top outlet stream from the demethanizer preferentially contains up to 3 mole percent of CO₂ and the majority of methane and small portion of any hydrocarbon heavier than methane, a split portion of this stream is taken and routed to cryogenic CO₂ removal section, in which a molecular sieve that forms a physical adsorption column is used to extract pure CO₂ as a product stream, then purified stream is routed to the liquefaction section where only two stages of coil-wound exchangers with a Semi-C3-MR cycle are used to liquefy natural gas. This present invention process is suited for LNG production in small-scale. This zeolite-based small-scale LNG process can be integrated with the design of any new natural gas facility and the technology can also be retrofitted to existing natural gas liquid (NGL) recovery plants, allowing for co-production of LNG and CO₂ with high purity.

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First Claim