DECARBOXYLATIVE CONJUGATE ADDITIONS AND APPLICATIONS THEREOF
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United States of America Patent
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Aug 29, 2024
app pub date -
Apr 19, 2024
filing date -
Jun 5, 2015
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Abstract
Synthetic methods are described herein operable to efficiently produce a wide variety of molecular species through conjugate additions via decarboxylative mechanisms. For example, methods of functionalization of peptide residues are described, including selective functionalization of peptide C-terminal residues. In one aspect, a method of peptide functionalization comprises providing a reaction mixture including a Michael acceptor and a peptide and coupling the Michael acceptor with the peptide via a mechanism including decarboxylation of a peptide reside.
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