Recovery of non-ferrous metals by thermal treatment of solutions containing non-ferrous and iron sulphates

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United States of America Patent

PATENT NO 4224122
SERIAL NO

05940937

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The specification discloses a method for recovering non-ferrous metals such as zinc or copper from their concentrates, ores or any other metal containing materials into a solution containing these non-ferrous metals as sulphates and a minimal amount of dissolved iron. The resultant solution is suited without or with minimum pre-purification treatment for conventional electrowinning processes to recover such non-ferrous metals with less difficulties than the previous methods involving complex iron-removal processing. There is disclosed a method for recovering at least one non-ferrous metal soluble in sulphuric acid from a strong sulphuric acid solution containing said metal and iron as sulphates, said method comprising the following consecutive steps: subjecting said solution in a sub-divided form to thermal decomposition in a fluidized bed reactor at a temperature of from 600.degree. to 750.degree. C. with 20-150% excess air for an average retention time of 1-12 hours to obtain calcine containing ferric oxide and the sulphate of said non-ferrous metal; leaching said non-ferrous metal sulphate out from said calcine with water or dilute sulphuric acid solutions; separating said leach solution containing said non-ferrous metal sulphate from the residue; and recovering said non-ferrous metal from said leach solution, via electrolysis or any other method.

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Patent Owner(s)

  • PROVINCIAL HOLDINGS LTD. C/O DEPARTMENT OF COMMERCE AND DEVELOPMENT

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Boorman, Roy S Fredericton, CA 5 63
Salter, Robert S Fredericton, CA 24 182
Wilkomirsky, Igor A E Fredericton, CA 4 52

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