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Abstract

A novel process is disclosed for the preparation of polyphenylene ethers by an oxidative coupling reaction. The process comprises oxidatively coupling a phenolic compound in the presence of a catalyst which comprises a copper complex of a copper compound with an N,N-disubstituted alkylene or cycloalkylene diamine having from 2 to 3 carbon atoms between the nitrogen atoms and whose substituents on the two nitrogen atoms are isopropyl or alpha tertiary alkyl, a tertiary amine, a bromine-containing compound and dimethyl amine. Unexpected short reaction times are obtained and the high molecular weight product increases in molecular weight and shows a marked decrease in bound nitrogen after moulding.

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First Claim