
US Patent No: 4,528,311
Number of patents in Portfolio can not be more than 2000
Ultraviolet absorbing polymers comprising 2-hydroxy-5-acrylyloxyphenyl-2H-benzotriazoles
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Jul 9, 1985
Issued date -
Jul 11, 1983
filing date -
06/512,860
serial no -
Expired
status

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Abstract
Ultraviolet light absorbing polymer compositions comprising copolymers of 2-Hydroxy-5-acrylyloxyphenyl-2H-benzotriazoles with one or more other monomers copolymerizable therewith, particularly acrylic monomers are useful in the manufacture of occular devices, particularly intraoccular lenses and contact lenses. Polymers of the disclosed benzotriazoles may be added to other organic materials to impart ultraviolet absorbing properties thereo.
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First Claim
Related Publications
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- 15 United States
- 10 France
- 8 Japan
- 7 China
- 5 Korea
- 2 Other
Patent Owner(s)
| Patent Owner | Address | Total Patents |
|---|---|---|
| IOLAB CORPORATION | CLAREMONT, CA | 30 |
International Classification(s)
- [Classification Symbol]
- [Patents Count]
Inventor(s)
| Inventor Name | Address | # of filed Patents | Total Citations |
|---|---|---|---|
| Beard, Charles D | Montchanin, DE | 5 | 305 |
| Doddi, Namassivaya | Upland, CA | 10 | 505 |
| Yamada, Akira | Hyogo, JP | 352 | 2273 |
Cited Art
| Patent Info | (Count) | # Cites | Year |
|---|---|---|---|
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| 4,276,401 N-Heterocyclic substituted acryloyl polymeric compounds | 15 | 1979 | |
| 4,278,590 2-[2-Hydroxy-3,5-di-tert-octylphenyl]-2H-Benzotriazole and stabilized compositions | 38 | 1979 | |
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| 4,310,650 Ultraviolet absorbing copolymers | 18 | 1980 | |
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| 4,260,768 Copolymerizable, ultraviolet light absorber 2-(2H-benzotriazol-2-yl)-4-alkylphenol acrylic acid esters | 7 | 1980 | |
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| 4,233,430 Anti-solar acrylamide derivative polymers, method of making the same and cosmetic compositions containing the same | 23 | 1979 | |
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| 4,304,895 Ultraviolet absorbing corneal contact lenses | 113 | 1976 | |
Patent Citation Ranking
Forward Cites
| Patent Info | (Count) | # Cites | Year |
|---|---|---|---|
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| 5,866,635 UV-absorbing benzotriazoles having a styrene group | 8 | 1998 | |
| 6,244,707 UV blocking lenses and material containing benzotriazoles and benzophenones | 20 | 1998 | |
| 6,353,069 High refractive index ophthalmic device materials | 35 | 2000 | |
| 6,528,602 Foldable ophthalmic and otorhinolaryngological device materials | 36 | 2000 | |
| 6,406,739 Coating compositions and methods for reducing edge glare in implantable ophthalmic lenses | 15 | 2000 | |
| 6,632,887 Coating compositions and methods for reducing edge glare in implantable ophthalmic lenses | 5 | 2002 | |
| 6,703,466 Foldable intraocular lens optics having a glassy surface | 13 | 2002 | |
| 7,119,210 Dual function UV-absorbers for ophthalmic lens materials | 9 | 2004 | |
| 7,396,942 Dual function UV-absorbers for ophthalmic lens materials | 6 | 2006 | |
| 7,585,900 Low-tack ophthalmic and otorhinolaryngological device materials | 3 | 2007 | |
| 7,691,918 Intraocular lenses with unique blue-violet cutoff and blue light transmission characteristics | 3 | 2007 | |
| 7,709,652 Dual function UV-absorbers for ophthalmic lens materials | 1 | 2008 | |
| 7,790,824 High refractive index ophthalmic device materials | 0 | 2008 | |
| 7,781,571 Ophthalmic lens materials containing chromophores that absorb both UV and short wavelength visible light | 0 | 2008 | |
| 7,728,051 Ophthalmic lens materials containing chromophores that absorb both UV and short wavelength visible light | 6 | 2008 | |
| 7,790,825 High refractive index ophthalmic device materials | 1 | 2009 | |
| 8,153,703 UV/visible light absorbers for ophthalmic lens materials | 1 | 2009 | |
| 8,324,256 Tri-functional UV-absorbing compounds and use thereof | 1 | 2009 | |
| 8,148,445 Ophthalmic and otorhinolaryngological device materials containing a multi-arm PEG macromer | 0 | 2010 | |
| 8,119,830 Dual function UV-absorbers for ophthalmic lens materials | 0 | 2010 | |
| 8,232,326 UV/visible light absorbers for ophthalmic lens materials | 0 | 2012 | |
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| 4,719,248 Ultraviolet blocking agents for contact lenses | 42 | 1985 | |
| 5,089,180 Method of preparing composite single-piece intraocular lenses with colored haptics | 5 | 1989 | |
| 6,359,024 Method for polymerizing contact lenses | 18 | 1998 | |
| 5,945,465 Method for polymerizing contact lenses having UV absorbing properties | 12 | 1998 | |
| 5,914,355 Method for making contact lenses having UV absorbing properties | 11 | 1998 | |
| 6,153,760 Method for making contact lenses having UV absorbing properties | 13 | 1999 | |
| 6,364,934 Method of making ocular devices | 7 | 2000 | |
| 6,776,934 Method for polymerizing lenses | 4 | 2001 | |
| 6,465,538 Method for polymerizing contact lenses | 18 | 2001 | |
| 6,762,264 Contact lens material | 15 | 2002 | |
| 7,276,544 Process for manufacturing intraocular lenses with blue light absorption characteristics | 6 | 2003 | |
| 6,921,802 Contact lens materials | 9 | 2004 | |
| 7,495,061 High refractive-index, hydrophilic monomers and polymers, and ophthalmic devices comprising such polymers | 1 | 2005 | |
| 7,825,257 Synthesis of benzotriazole monomer | 0 | 2008 | |
| 7,781,496 High refractive-index, hydrophilic monomers and polymers, and ophthalmic devices comprising such polymers | 0 | 2008 | |
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| 5,164,462 Ultraviolet light absorbing compounds and silicone compositions | 35 | 1991 | |
| 5,376,737 Methods for benefitting polymers | 2 | 1992 | |
| 5,352,753 Ultraviolet light absorbing compounds, silicone compositions and methods for making same | 6 | 1992 | |
| 5,397,848 Enhancing the hydrophilicity of silicone polymers | 126 | 1993 | |
| 5,466,768 Ultraviolet light absorbing compounds, silicone compositions and methods for making same | 13 | 1994 | |
| 8,043,371 Intraocular lenses having a visible light-selective-transmissive-region | 0 | 2004 | |
| 7,278,737 Ophthalmic devices having a highly selective violet light transmissive filter and related methods | 22 | 2005 | |
| 8,188,203 Copolymerizable azo compounds and articles containing them | 1 | 2008 | |
| 8,360,576 Copolymerizable methine and anthraquinone compounds and articles containing them | 0 | 2008 | |
| 8,047,650 Ophthalmic devices having a highly selective violet light transmissive filter and related methods | 1 | 2009 | |
| 8,388,681 Intraocular lenses having a visible light-selective-transmissive-region | 0 | 2011 | |
| 8,292,428 Ophthalmic devices having a highly selective violet light transmissive filter and related methods | 0 | 2011 | |
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| 8,048,155 Intraocular implant devices | 1 | 2003 | |
| 7,776,088 Intraocular lens system and method for power adjustment | 2 | 2005 | |
| 7,485,144 Methods of adjusting the power of an intraocular lens | 4 | 2006 | |
| 8,361,145 Accommodating intraocular lens system having circumferential haptic support and method | 0 | 2006 | |
| 7,637,947 Accommodating intraocular lens system having spherical aberration compensation and method | 0 | 2006 | |
| 8,303,656 Adaptive optic lens and method of making | 0 | 2007 | |
| 8,158,712 Polymeric materials suitable for ophthalmic devices and methods of manufacture | 0 | 2008 | |
| 8,328,869 Accommodating intraocular lenses and methods of use | 0 | 2008 | |
| 8,314,927 Systems and methods for testing intraocular lenses | 0 | 2008 | |
| 8,425,599 Accommodating intraocular lenses and methods of use | 0 | 2011 | |
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| 5,981,076 UV protected syndiotactic polystyrene overlay films | 6 | 1996 | |
| 6,008,302 Polyolefin bound ultraviolet light absorbers | 6 | 1997 | |
| 6,120,901 UV protected syndiotactic polystyrene overlay films | 6 | 1998 | |
| 6,352,764 Multi-layer articles including UV-absorbing polymeric compositions | 2 | 1999 | |
| 6,312,807 UV-absorbing core/shell particles | 5 | 1999 | |
| 6,251,521 Polymeric compositions | 3 | 1999 | |
| 6,235,375 Polyolefin bound ultraviolet light absorbers | 1 | 1999 | |
| 6,464,817 Polyolefin bound ultraviolet light absorbers | 1 | 2001 | |
| 6,582,790 Polyolefin bound ultraviolet light absorbers | 1 | 2002 | |
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| 7,628,810 Mask configured to maintain nutrient transport without producing visible diffraction patterns | 7 | 2004 | |
| 7,976,577 Corneal optic formed of degradation resistant polymer | 0 | 2005 | |
| 8,079,706 Method and apparatus for aligning a mask with the visual axis of an eye | 0 | 2006 | |
| 8,343,215 System and method for increasing the depth of focus of the human eye | 0 | 2008 | |
| D656526 Ocular mask | 0 | 2009 | |
| 8,287,592 Ophthalmic devices having a degradation resistant polymer | 0 | 2011 | |
| D681086 Ocular mask | 0 | 2012 | |
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| 5,384,235 Photographic elements incorporating polymeric ultraviolet absorbers | 19 | 1992 | |
| 5,858,633 Photographic elements containing 3-alkyl group substituted 2-hydroxyphenylbenzotriazole UV absorbing polymers | 2 | 1997 | |
| 6,312,880 Color photographic silver halide print media | 2 | 1999 | |
| 6,280,916 Silver halide reflection support print media | 3 | 1999 | |
| 6,268,116 Scavenger free photographic silver halide print media | 3 | 1999 | |
| 7,569,254 Nanocomposite materials comprising high loadings of filler materials and an in-situ method of making such materials | 1 | 2005 | |
| 7,455,886 Nanocomposite materials and an in-situ method of making such materials | 3 | 2005 | |
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| 7,446,157 Nanohybrid polymers for ophthalmic applications | 3 | 2004 | |
| 7,842,367 Ultra violet, violet, and blue light filtering polymers for ophthalmic applications | 0 | 2006 | |
| 7,857,848 Infinite refractive index gradient (IRIG) polymers for ocular implant and contact lens applications | 0 | 2006 | |
| 7,771,470 Ophthalmic apparatuses and methods | 0 | 2006 | |
| 7,745,555 Nanohybrid polymers for ophthalmic applications | 2 | 2007 | |
| 8,048,972 Nanohybrid polymers for ophthalmic applications | 0 | 2010 | |
| 8,420,753 Nanohybrid polymers for ophthalmic applications | 0 | 2011 | |
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| 6,577,387 Inspection of ophthalmic lenses using absorption | 31 | 2000 | |
| 6,838,679 Missing lens detection system and method | 0 | 2001 | |
| 7,057,186 Missing lens detection system and method | 1 | 2002 | |
| 7,879,288 Method and apparatus of sterilization using monochromatic UV radiation source | 1 | 2004 | |
| 8,021,608 Method and apparatus of sterilization using monochromatic UV radiation source | 2 | 2010 | |
| 8,318,089 Method and apparatus of sterilization using monochromic UV radiation source | 0 | 2011 | |
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| 5,290,892 Flexible intraocular lenses made from high refractive index polymers | 118 | 1993 | |
| 5,433,746 Flexible intraocular lenses made from high refractive index polymers | 30 | 1993 | |
| 5,403,901 Flexible, high refractive index polymers | 44 | 1993 | |
| 5,674,960 Flexible high refractive index, cross-linked, acrylic copolymers | 32 | 1996 | |
| 5,861,031 Intraocular lens from arylalkyl(meth)acrylate polymer(s) | 28 | 1997 | |
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| 5,693,095 High refractive index ophthalmic lens materials | 81 | 1996 | |
| 6,015,842 Method of preparing foldable hydrophilic ophthalmic device materials | 31 | 1997 | |
| 5,891,931 Method of preparing foldable high refractive index acrylic ophthalmic device materials | 53 | 1997 | |
| 5,922,821 Ophthalmic lens polymers | 20 | 1997 | |
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| 4,963,160 Reactive uv absorbing compositions and method of preparing lenses therefrom | 26 | 1989 | |
| 5,298,033 Ultraviolet absorbing lenses and methods of manufacturing thereof | 12 | 1993 | |
| 5,399,692 Ultraviolet absorbing benzophenone sulfonic acid derivatives | 17 | 1993 | |
| 5,480,927 Method of increasing the concentration of radiation-absorbing agents in optical and ophthalmic lenses | 6 | 1994 | |
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| 7,078,421 Substituted phenylacetic acids | 0 | 2003 | |
| 7,199,259 Resolution of .alpha.-(phenoxy)phenylacetic acid derivatives | 4 | 2003 | |
| 7,642,358 Substituted phenylacetic acids | 0 | 2006 | |
| 7,714,131 Process for the stereoselective preparation of (−)-halofenate and derivatives thereof | 0 | 2006 | |
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| 6,448,304 Optical materials having good ultraviolet absorbability and method for producing them | 4 | 2000 | |
| 6,441,119 Optical materials having good ultraviolet absorbability and method for producing them | 9 | 2000 | |
| 6,673,888 Optical materials having good ultraviolet absorbability and method for producing them | 6 | 2002 | |
| 7,009,025 Optical materials having good ultraviolet absorbability and method for producing them | 1 | 2004 | |
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| 4,785,063 Copolymerizable 2-(2'-hydroxy-5'-acryloyloxyalkyl)-2H-benzotriazoles | 52 | 1986 | |
| 4,996,326 Novel 2-(2-hydroxyphenyl)-benzotriazole derivatives, substituted by branched long chain alkyl groups containing ester moieties | 11 | 1990 | |
| 6,201,000 Use of selected benzotriazole derivatives for protecting human and animal skin and hair from the harmful effects of UV radiation | 7 | 1999 | |
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| 6,100,009 Image recording medium, image recording method and heat coloring polymer compound | 7 | 1998 | |
| 6,329,120 Image recording medium, image recording method and heat coloring polymer compound | 3 | 2000 | |
| 6,329,121 Image recording medium, image recording method and heat coloring polymer compound | 5 | 2000 | |
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| 8,003,132 Compositions comprising an ultraviolet radiation-absorbing polymer | 0 | 2009 | |
| 8,025,868 Compositions comprising an ultraviolet radiation-absorbing polymer | 0 | 2009 | |
| 7,993,680 Compositions comprising an ultraviolet radiation-absorbing polymer | 0 | 2009 | |
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| 5,039,459 Method of forming shaped hydrogel articles including contact lenses | 110 | 1989 | |
| 5,770,637 Anti-bacterial, UV absorbable, tinted, metal-chelating polymers | 14 | 1996 | |
| 6,218,463 Ocular devices manufactured with free radical-polymerizable latent ultra-violet absorbers | 15 | 1998 | |
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| 6,638,388 Laminating film and laminating method using it | 4 | 2001 | |
| 6,802,925 Laminating film and lamination process using the same | 5 | 2002 | |
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| 6,936,659 Polymer-bonded functional agents | 0 | 2002 | |
| 7,253,229 Polymer-bonded functional agents | 0 | 2005 | |
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| 4,716,234 Ultraviolet absorbing polymers comprising 2-(2'-hydroxy-5'-acryloyloxyalkoxyphenyl)-2H-benzotriazole | 67 | 1986 | |
| 4,803,254 Vinylsilylalkoxy arylbenzotriazole compounds and UV absorbing compositions made therefrom | 47 | 1987 | |
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| 7,452,602 Vinylidene fluoride-based resin film | 1 | 2005 | |
| 8,303,875 Method for producing vinylidene fluoride resin transparent film | 0 | 2008 | |
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| 6,194,330 Polymer latex for ultraviolet absorbtion on fabric | 2 | 1998 | |
| 6,482,757 Polymer latex for ultraviolet absorption on different substrates | 4 | 2001 | |
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| 4,975,478 Weather-resistant polyacetal resin composition and molded articles therefrom | 9 | 1989 | |
| RE34141 Weather-resistant polyacetal resin composition and molded articles therefrom | 3 | 1991 | |
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| 5,617,154 Light filtering contact lens | 48 | 1994 | |
| 5,846,457 Light filtering contact lens method | 16 | 1997 | |
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| 5,133,745 Ultraviolet absorbing hydrogels | 27 | 1991 | |
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| 6,251,986 Paint resin emulsion having weatherability | 4 | 1998 | |
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| 7,713,628 Actinic radiation curable coating compositions | 1 | 2005 | |
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| 6,683,124 Fluorescent pigment compositions | 2 | 2001 | |
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| 6,187,835 Radiation-curable optical fiber coatings having reduced yellowing and fast cure speed | 20 | 1998 | |
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| 6,147,170 UV stabilized ethylene copolymers | 2 | 1998 | |
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| 7,989,572 Polyvinyl ultraviolet light absorbers for personal care | 0 | 2008 | |
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| 7,915,322 Polymerizable water-soluble or alcohol-soluble ultraviolet absorber | 0 | 2008 | |
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| 6,998,425 UV curable coating compositions and uses thereof | 9 | 2003 | |
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| 5,891,961 Coating composition and coating method | 3 | 1997 | |
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| 5,147,902 Ultraviolet light absorbing ocular lens | 37 | 1991 | |
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| 6,132,462 Copolymers formed from three components and intraocular lenses made thereof | 26 | 1998 | |
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| 5,252,628 Method of making photoprotective hydrophilic polymers and ocular devices thereof | 5 | 1989 | |
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| 6,432,137 High refractive index silicone for use in intraocular lenses | 18 | 2000 | |
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| 6,277,940 Material for a soft intraocular lens | 19 | 1999 | |
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| 7,323,480 Substituted triazoles as modulators of PPAR and methods of their preparation | 1 | 2005 | |
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| 6,096,846 Ultraviolet absorbing base material | 3 | 1998 | |
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| 7,659,325 Functionalized dyes and use thereof in ophthalmic lens material | 1 | 2005 | |
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| 6,653,422 Foldable ophthalmic and otorhinolaryngological device materials | 16 | 2003 | |
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| 6,036,891 Polymerizable hydrophilic ultraviolet light absorbing monomers | 8 | 1998 | |
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| 7,354,980 High refractive index polymers for ophthalmic applications | 1 | 2005 | |
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| 5,467,217 Light valve suspensions and films containing UV absorbers and light valves containing the same | 36 | 1993 | |
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| 4,612,358 UV-absorbing monomer and polymers thereof | 25 | 1985 | |
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| 5,712,324 U-V curable weather resistant coatings made by a cold-cast process | 7 | 1996 | |
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| 5,637,726 UV-absorbing benzotriazoles having a styrene group | 17 | 1996 | |
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| 5,872,172 Methods for the preparation of liquid silicone rubber base and liquid silicone rubber composition | 2 | 1997 | |
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| 5,633,504 Inspection of optical components | 25 | 1995 | |
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| 6,835,939 Missing lens detection system and method | 0 | 2003 | |
| 8,447,086 Lens capsule size estimation | 0 | 2010 | |
Maintenance Fees
| Fee | Large entity fee | small entity fee | micro entity fee | due date |
|---|
| Fee | Large entity fee | small entity fee | micro entity fee |
|---|---|---|---|
| Surcharge after expiration - Late payment is unavoidable | $700.00 | $350.00 | $175.00 |
| Surcharge after expiration - Late payment is unintentional | $1,640.00 | $820.00 | $410.00 |