Continuous process for the gaseous-phase preparation of trichlorotrifluoroethane, dichlorotetrafluoroethane and monochloropentafluoroethane in controlled proportions

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United States of America Patent

PATENT NO 4605798
SERIAL NO

06324823

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Abstract

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This invention relates to a continuous gaseous-phase process for the preparation of trichlorotrifluoroethane, dichlorotetrafluoroethane and monochloropentafluoroethane, in predetermined proportions, from tetrachloroethylene, chlorine and hydrofluoric acid in the presence of a catalyst. The process is characterized by the combination of two chlorination-fluorination reactors in sequence, a parallel fluorination-dismutation reactor, and a separation unit for extracting the desired products and recycling recovered hydrofluoric acid and non-fluorinated or insufficiently fluorinated products. The process advantageously yields dichlorotetrafluoroethane containing less than 7% asymmetric isomer, and trichlorotrifluoroethane containing less than 2% asymmetric isomer.

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Patent Owner(s)

Patent OwnerAddress
PCUK PRODUITS CHIMIQUES UGINE KUHLMANNTOUR MANHATTAN LA DEFENSE 2 5&6 PLACE DE L'IRIS 92400 COURBEVOIE

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Abel, Michel Pierre-Benite, FR 1 19
Fine, Francois St. Laurent de Mure, FR 2 20
Foulletier, Louis Oullins, FR 11 121
Verot, Yvan Ecully, FR 3 21

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