Low temperature catalysts for methanol production
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United States of America Patent
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Sep 30, 1986
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N/A
app pub date -
Dec 23, 1985
filing date -
Mar 12, 1985
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Abstract
A catalyst and process useful at low temperatures (below about 160.degree. C.) and preferably in the range 80.degree.-120.degree. C. used in the production of methanol from carbon monoxide and hydrogen is disclosed. The catalyst is used in slurry form and comprises a complex reducing agent derived from the component structure NaH--RONa--M(OAc).sub.2 where M is selected from the group consisting of Ni, Pd, and Co and R is a lower alkyl group containing 1-6 carbon atoms. This catalyst is preferably used alone but is also effective in combination with a metal carbonyl of a group VI (Mo, Cr, W) metal. The preferred catalyst precursor is Nic (where M=Ni and R=tertiary amyl). Mo(CO).sub.6 is the preferred metal carbonyl if such component is used. The catalyst is subjected to a conditioning or activating step under temperature and pressure, similar to the parameters given above, to afford the active catalyst.
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- ASSOCIATED UNIVERSITIES, INC.
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Inventor(s)
Inventor Name | Address | # of filed Patents | Total Citations |
---|---|---|---|
Mahajan, Devinder | 14 Locust Ct., Selden, NY 11784 | 21 | 304 |
O'Hare, Thomas E | 11 Geiger Pl., Huntington Station, NY 11746 | 6 | 120 |
Sapienza, Richard S | 1 Miller Ave., Shoreham, NY 11786 | 13 | 153 |
Slegeir, William A | 7 Florence Rd., Hampton Bays, NY 11946 | 11 | 129 |
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