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Abstract

A method and composition for stimulating subterranean formations containing iron deposits. The composition comprises an admixture of (i) at least one member selected from the group consisting of hydroxylamine hydrochloride, hydroxylamine hydrobromide, hydroxylamine sulfate, hydrazine monohydrochloride, hydrazine dihydrochloride, hydrazine sulfate, hydrazine monobromide, hydrazine dibromide, hydrazine monoiodide, hydrazine diiodide and hydroquinone together with (ii) at least one member selected from the group consisting of gluconodeltalactone, citric acid, salts of citric acid, ethylenediaminetetraacetic acid, salts of ethylenediamianetetraacetic acid, nitrilotriacetic acid, salts of nitrilotriacetic acid, hydroxyethylethylenediaminetriacetic acid, and salts of hydroxyethylethylenediaminetriacetic acid and (iii) a catalytic amount of a solubilized salt of a compound capable of providing cupric, cuprous, nickel, zinc ions or mixtures thereof. The method comprises contacting the subterranean formation in an appropriate manner with the above-described composition present in an amount sufficient to sequester iron. When the treating fluid used in stimulating the subterranean formation is substantially non-acidic, the compounds of group (ii), above, can be omitted from the above-described composition and iron still is sequestered.

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