US Patent No: 4,755,425

Number of patents in Portfolio can not be more than 2000

Retroreflective sheet coated with silica layer

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Abstract

Retroreflective sheeting has been improved by a coating comprising silica and a transparent polymer selected from aliphatic polyurethanes and polyvinyl chloride copolymers having a minor amount of a comonomer containing at least one carboxylic acid or hydroxyl moiety. Silica comprises 10-80 weight percent of the transparent protective coating. For example, a solution or dispersion of polyurethane is mixed with a silica sol and possibly other ingredients (e.g. wetting agent, UV light absorber and adhesion promoter), and the composition is coated onto the retroreflective sheet and dried. The coated retroreflective sheeting has superior soil and dew repellancy, retaining a higher percentage of original brightness after exposure to dirt and/or dew conditions.

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First Claim

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Patent Owner(s)

Patent OwnerAddressTotal Patents
MINNESOTA MINING AND MANUFACTURING COMPANYST PAUL, MN6633

International Classification(s)

Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Huang, Tzu L J Woodbury, MN 1 27

Cited Art

Patent Info (Count) # Cites Year
 
GENERAL ELECTRIC COMPANY (2)
4,311,763 Silicone resin coating composition 19 1980
4,476,281 Silicone resin coating composition 28 1982
 
MINNESOTA MINING AND MANUFACTURING COMPANY (2)
4,367,920 Retroflective sheeting 68 1981
4,505,967 High-angularity retroreflective sheeting and method for manufacture 59 1983
 
ASAHI GLASS COMPANY, LIMITED (1)
4,442,177 Alkyl ether methylolmelamine coating composition, coating process and transparent product 8 1981
 
COTEK COMPANY (1)
4,596,745 Non-glare coating 24 1984
 
EKA NOBEL AB (1)
4,600,735 Soil-repellent coating composition 8 1985
 
EXXONMOBIL RESEARCH AND ENGINEERING COMPANY (1)
8,202,403 Core de-entrainment device for vessels with tangential inlets 6 2008
 
GENERAL MOTORS CORPORATION (1)
4,528,319 Sag control of high solid polyurethane clearcoats by urea thixotrope/silica systems 17 1984
 
IMPERIAL CHEMICAL INDUSTRIES PLC (1)
4,409,285 Surface-modifying coating compositions 44 1981
 
LORD CORPORATION (1)
4,513,112 High build, ambient cure coating compositions 8 1984
 
PPG INDUSTRIES, INC. (1)
4,522,958 High-solids coating composition for improved rheology control containing chemically modified inorganic microparticles 109 1983
 
ROHM GMBH (1)
4,576,864 Water spreading plastic material, method for its manufacture and its use as a glazing and roofing material 37 1985
 
SEIKOH CHEMICALS COMPANY, LIMITED (1)
4,554,214 Casting coating 10 1982
 
TORAY INDUSTRIES, INC. (1)
4,211,823 Tintable coatings and articles having such coatings 86 1979

Patent Citation Ranking

Forward Cites

Patent Info (Count) # Cites Year
 
3M INNOVATIVE PROPERTIES COMPANY (8)
6,352,758 Patterned article having alternating hydrophilic and hydrophobic surface regions 39 1998
6,132,861 Retroreflective articles including a cured ceramer composite coating having a combination of excellent abrasion, dew and stain resistant characteristics 35 1998
6,265,061 Retroflective articles including a cured ceramer composite coating having abrasion and stain resistant characteristics 17 1999
6,245,833 Ceramer composition incorporating fluoro/silane component and having abrasion and stain resistant characteristics 24 1999
6,376,576 Ceramer composition incorporating fluoro/silane component and having abrasion and stain resistant characteristics 8 2000
7,195,360 Prismatic retroreflective article and method 2 2004
7,347,571 Prismatic retroreflective article with fluorine- or silicon-containing prisms 1 2005
7,547,105 Prismatic retroreflective article with cross-linked image layer and method of making same 0 2007
 
MINNESOTA MINING AND MANUFACTURING COMPANY (7)
5,104,929 Abrasion resistant coatings comprising silicon dioxide dispersions 101 1989
5,087,508 Dew and frost resistant signs 4 1990
5,914,162 Coating for metal surfaces of unsaturated polymer and colloidal inorganic particles 42 1992
5,508,105 Thermal print receptive and frangible retrorefelective polymeric sheetings 27 1994
5,677,050 Retroreflective sheeting having an abrasion resistant ceramer coating 54 1995
5,820,978 Durability improved colloidal silica coating 9 1995
5,939,182 Polymeric article having improved hydrophilicity and a method of making the same 30 1996
 
AVERY DENNISON CORPORATION (4)
5,514,441 Retroreflective sheeting with improved topcoat 19 1994
6,054,208 Film forming mixtures, image bearing films and image bearing retroreflective sheeting 32 1998
8,088,492 Thermal transfer image receiving sheet and method 0 2004
7,504,156 Dew resistant coatings 0 2005
 
REFLEXITE CORPORATION (3)
5,512,219 Method of casting a microstructure sheet having an array of prism elements using a reusable polycarbonate mold 52 1994
5,617,247 Light signaling device 4 1996
5,888,618 Fire-resistant, retroreflective structure 21 1996
 
THE STANDARD REGISTER COMPANY (2)
6,376,135 Image bonding treatment for retroreflective surfaces 4 1999
6,416,911 Image bonding treatment of retroreflective surfaces 3 2001
 
BAYER AKTIENGESELLSCHAFT (1)
6,927,251 Mixtures of aqueous binders 2 2001
 
KIMBERLY-CLARK WORLDWIDE, INC. (1)
7,703,456 Facemasks containing an anti-fog / anti-glare composition 2 2003
 
ORAFOL AMERICAS INC. (1)
5,648,145 Fire-resistant, retroreflective structure 12 1993