Halogen-free flameproof molding materials

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United States of America Patent

PATENT NO 4914144
SERIAL NO

07285662

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Abstract

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A flameproof, halogen-free thermoplastic molding material contains, based on the molding material consisting of A, B, C, D and E, (A) 40 to 95% by weight of a thermoplastic halogen-free aromatic polycarbonate based on a diphenol, (B) from 5 to 30% by weight of one or more halogen-free graft polymers obtained from, based on B, (b.sub.1) an elastomer (rubber), which accounts for from 40 to 80% by weight, and (b.sub.2) a graft shell on this elastomer which accounts for from 20 to 60% by weight, (C) from 5 to 50% by weight of one or more halogen-free thermoplastic copolymers consisting of, based on C, from 50 to 95% by weight of styrene, .alpha.-methylstyrene, styrene which is substituted in the nucleus, methyl methacrylate or a mixture of these, and from 50 to 5% by weight of (meth)acrylonitrile, methyl methacrylate, maleic anhydride, N-substituted maleimide or a mixture of these, (D) 1 to 25% by weight of one or more halogen-free phosphorus compounds of the formula ##STR1## where R.sup.1, R.sup.2 and R.sup.3 independently of one another are each halogen-free C.sub.1 -C.sub.8 -alkyl or halogen-free C.sub.6 -C.sub.20 -aryl and n is 0 or 1, and (E) from 0.05 to 5% by weight of a tetrafluoroethylene polymer. In the molding material, the elastomer (b.sub.1) is prepared by polymerizing a monomer mixture of (b.sub.1 a.sub.1) from 70 to 99.9% by weight, based on b.sub.1), of one or more alkyl acrylates where alkyl is of 1 to 8 carbon atoms, (b.sub.1 a.sub.2) from 0 to 30% by weight, based on (b.sub.1), of one or more further copolymerizable monoethylenically unsaturated monomers and b.sub.1 a.sub.3) from 0.1 to 5% by weight, based on B.sub.1), of a copolymerizable polyfunctional, crosslinking monomer. The molding material is used for the production of shaped articles.

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Patent Owner(s)

Patent OwnerAddress
BASF AKTIENGESELLSCHAFT67056 LUDWIGSHAFEN

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Blum, Dieter W Limburgerhof, DE 15 237
Brandi, Hermann Schiffestadt, DE 1 36
McKee, Graham E Weinheim, DE 26 283
Muehlbach, Klaus Heppenheim, DE 48 322

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