Cold-setting moulding binders and their use (phenols and gaseous acetals)

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United States of America Patent

PATENT NO 4929649
SERIAL NO

07228931

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Abstract

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The binder serves to produce foundry moulds and comprises a solution (preferably an aqueous solution) of aldehyde reactive phenol substances and gaseous acetals (preferably dimethyl formal) as reaction partners and strong acids, e.g. sulphuric acid and sulphonic acids as a catalyst. The acetal is in this system hydrolysed by the acid, the basic aldehyde being formed, which will react with the aldehyde reactive phenol substance accompanied by cross-linking. The acid serves thereby simultaneously as a cross-linking catalyst. In principle, it is possible to regard as 'aldehyde reactive phenol substances' any phenolic compounds which can in the acid range cross-link more or less spontaneously with aldehydes. Preferably, these are resorcinol or resorcinol products, e.g. resorcinol pitch or precondensates formed with a shortfall of aldehyde, e.g. based on resorcinol formaldehyde, phenol resorcinol formaldehyde or resorcinol melamine formaldehyde. To produce foundry moulds, a granular basic moulding material, e.g. sand, the solution of the aldehyde reactive phenol substance and the acid are used to produce a moulding mixture which is then caused to set by passing the gaseous acetal (formal) through it. The aldehyde cross-linking of the aldehyde raective phenol substance in the acid medium, the process which takes place thereby, produces duroplasts (resites), which combine a very good thermal resistance and a low pollutants emission during casting with a high strength and negligible sensitivity to moisture in the mouldings produced, features which make them extremely favorable.

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Patent Owner(s)

Patent OwnerAddress
HUTTENES-ALBERTUS CHEMISCHE WERKE GMBH A CORP OF GERMANYNot Provided

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Jerman, Franz Dusseldorf, DE 1 2
Ladegourdie, Gerard Kaarst, DE 4 5
Lingemann, Dirk Neuss, DE 1 2
Seiss, Willi Neuss-Allerheiligen, DE 2 10
Torbus, Marek Dusseldorf, DE 8 40
Vujevic, Aleksandar Ratingen, DE 3 13

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