Production of detergent range alcohols and ketones using acetylacetonate catalysts
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United States of America Patent
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Dec 18, 1990
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N/A
app pub date -
Oct 30, 1989
filing date -
Oct 30, 1989
priority date (Note) -
Expired
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Abstract
A process for the production of detergent range alcohols and ketones by reacting an alkane with a hydroperoxide in the presence of a transition metal acetylacetonate catalyst is described. Preferred hydroperoxides include cumene hydroperoxide and tertiary butyl hydroperoxide. The transition metal itself may be iron, ruthenium, chromium and mixtures thereof. If iron acetylacetonate is used as a catalyst, copper (II) acetate may be usefully employed as a co-catalyst.
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