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Abstract

A hollow glass waveguide such as an optical fibre comprises a glass cladding containing in excess of 90 mole % germanium dioxide, the balance of the cladding being made up of modifying oxides such as network modifiers and intermediate modifiers. The use of high concentrations of germanium dioxide results in the waveguide having good optical properties in the 9-11 .mu.m wavelength range e.g. low transmission losses. The incorporation of small quantities of modifying oxides produces improved physical properties e.g. better fibre drawing capability and reduced tendency to devitrification. A particularly preferred cladding contains 94 mole % GeO.sub.2, 3 mole % Na.sub.2 O and 3 mole % Al.sub.2 O.sub.3.

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First Claim