Disproportionation of alpha-olefin dimer to liquid lubricant basestock

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United States of America Patent

PATENT NO 5026948
SERIAL NO

07313401

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Abstract

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A process is disclosed for the preparation of low viscosity lubricant range hydrocarbons having high viscosity index which comprises: contacting olefinic dimer, or mixtures thereof, with a Group 6 metal oxide disproportionation catalyst on a solid support under disproportionation reaction conditions. The dimer comprises the product of the oligomerization of C.sub.6 -C.sub.20 alpha-olefins in contact with reduced chromium oxide catalyst on silica support. The disproportionation catalyst preparation includes treatment by oxidation at a temperature of 200.degree. C. to 900.degree. C. in the presence of an oxidizing gas and then treatment with a reducing agent at a temperature and a time sufficient to reduce said catalyst. The disproportionation reaction effluent is separated and lubricant range hydrocarbons recovered. The preferred disproportionation catalyst for the process is reduced tungsten oxide on silica support.

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Patent Owner(s)

Patent OwnerAddress
EXXONMOBIL CHEMICAL PATENTS INC13501 KATY FREEWAY HOUSTON TX 77079

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Forbus, Thomas R Newton, PA 9 104

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