Process of making a PTC composition by grafting method using two different crystalline polymers and carbon particles

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United States of America Patent

PATENT NO 5190697
SERIAL NO

07629249

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Abstract

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A process for producing PTC (positive temperature coefficient) self-resetting overcurrent protection elements using two different crystalline polymers with an organic peroxide and carbon black. The mixture is kneaded at an elevated temperature. The two crystalline polymers include different proportions of tertiary hydrogen atoms to carbon atoms, so that the desired PTC characteristics of a highly crystallized polymer can obtain the benefit of greater proportions of tertiary hydrogen in a less highly crystallized polymer. A high degree of grafting to carbon black that increases the number of polymer having unpaired electrons in the crystalline polymer mixture through the decomposition of organic peroxide. The resulting mixture tends to disperse the carbon black uniformly throughout the resulting mixture, and to position the carbon black in a three-dimensional matrix in which it is fixed by cross-linking. The uniform distribution of the carbon black reduces localized heating and thus minimizes resistance changes following repeated overcurrent conditions. The first crystalline polymer is selected from high density polyethylene, polyesters, fluorine-containing polymers and mixtures thereof. The second crystalline polymer is either low density polyethylene or medium density polyethylene.

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Patent Owner(s)

Patent OwnerAddress
DAITO COMMUNICATION APPARATUS CO LTDTOKYO

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Abe, Toshiaki Tokyo, JP 29 360
Ohkita, Kumakazu Chiba, JP 1 24
Sugaya, Shoichi Tokyo, JP 2 66
Ueno, Akira Yokohama, JP 118 677

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