
US Patent No: 5,272,871
Number of patents in Portfolio can not be more than 2000
Method and apparatus for reducing nitrogen oxides from internal combustion engine
Stats
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Dec 28, 1993
Issued date -
May 22, 1992
filing date -
07/887,133
serial no -
Expired
status

Importance
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US Family Size
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International Coverage
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Patent Longevity
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Forward Citations
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Abstract
Hydrogen gas from a hydrogen generator which creates hydrogen gas by the electrolysis of water or water vapor is supplied at the entrance to a catalyzer provided in an exhaust line. The catalyzer performs a catalytic reaction between hydrogen gas and nitrogen oxides to achieve decomposition into nitrogen gas and water vapor in the exhaust from an internal combustion engine. The nitrogen oxides are directly reduced with said hydrogen gas in a low temperature atmosphere not higher than 350.degree. C. to achieve efficient reduction in the nitrogen oxides. The improved method and apparatus provide a catalytic system with which the nitrogen oxides in the exhaust from a lean burnt engine or a diesel engine can be effectively reduced irrespective of the concentration of oxygen gas in the exhaust without impairing the good fuel economy of those engines.
First Claim
Related Publications
- 15 United States
- 10 France
- 8 Japan
- 7 China
- 5 Korea
- 2 Other
Patent Owner(s)
| Patent Owner | Address | Total Patents |
|---|---|---|
| KABUSHIKI KAISHA TOYOTA CHUO KENKYUSHO | AICHI-KEN | 847 |
International Classification(s)
- [Classification Symbol]
- [Patents Count]
Inventor(s)
| Inventor Name | Address | # of filed Patents | Total Citations |
|---|---|---|---|
| Abe, Katsushi | Aichi-ken, JP | 12 | 268 |
| Fukui, Masayuki | Kawasaki, JP | 60 | 498 |
| Kawahara, Kazuo | Aichi-gun, JP | 9 | 237 |
| Muraki, Hideaki | Aichi, JP | 23 | 822 |
| Oshima, Yujiro | Nagoya, JP | 18 | 591 |
| Yokota, Koji | Nagoya, JP | 28 | 641 |
Cited Art
| Patent Info | (Count) | # Cites | Year |
|---|---|---|---|
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| 4,484,444 Apparatus and methods of amplifying engine emissions by which to increase the overall engine efficiency | 4 | 1982 | |
Patent Citation Ranking
Forward Cites
| Patent Info | (Count) | # Cites | Year |
|---|---|---|---|
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| 6,843,051 Method and apparatus for controlling lean-burn engine to purge trap of stored NOx | 0 | 2000 | |
| 6,810,659 Method for determining emission control system operability | 2 | 2000 | |
| 6,708,483 Method and apparatus for controlling lean-burn engine based upon predicted performance impact | 3 | 2000 | |
| 6,629,453 Method and apparatus for measuring the performance of an emissions control device | 3 | 2000 | |
| 6,594,989 Method and apparatus for enhancing fuel economy of a lean burn internal combustion engine | 30 | 2000 | |
| 6,691,507 Closed-loop temperature control for an emission control device | 11 | 2000 | |
| 6,860,100 Degradation detection method for an engine having a NOx sensor | 2 | 2001 | |
| 6,694,244 Method for quantifying oxygen stored in a vehicle emission control device | 5 | 2001 | |
| 6,691,020 Method and system for optimizing purge of exhaust gas constituent stored in an emission control device | 2 | 2001 | |
| 6,650,991 Closed-loop method and system for purging a vehicle emission control | 2 | 2001 | |
| 6,615,577 Method and system for controlling a regeneration cycle of an emission control device | 20 | 2001 | |
| 6,604,504 Method and system for transitioning between lean and stoichiometric operation of a lean-burn engine | 6 | 2001 | |
| 6,553,754 Method and system for controlling an emission control device based on depletion of device storage capacity | 13 | 2001 | |
| 6,990,799 Method of determining emission control system operability | 7 | 2001 | |
| 7,168,239 Method and system for rapid heating of an emission control device | 8 | 2002 | |
| 7,111,450 Method for controlling the temperature of an emission control device | 11 | 2002 | |
| 7,032,572 Method for controlling an engine to obtain rapid catalyst heating | 5 | 2002 | |
| 6,925,982 Overall scheduling of a lean burn engine system | 1 | 2002 | |
| 6,868,827 Method for controlling transitions between operating modes of an engine for rapid heating of an emission control device | 20 | 2002 | |
| 6,769,398 Idle speed control for lean burn engine with variable-displacement-like characteristic | 27 | 2002 | |
| 6,758,185 Method to improve fuel economy in lean burn engines with variable-displacement-like characteristics | 25 | 2002 | |
| 6,745,747 Method for air-fuel ratio control of a lean burn engine | 19 | 2002 | |
| 6,735,938 Method to control transitions between modes of operation of an engine | 44 | 2002 | |
| 6,736,120 Method and system of adaptive learning for engine exhaust gas sensors | 10 | 2002 | |
| 6,736,121 Method for air-fuel ratio sensor diagnosis | 48 | 2002 | |
| 6,725,830 Method for split ignition timing for idle speed control of an engine | 8 | 2002 | |
| 6,715,462 Method to control fuel vapor purging | 22 | 2002 | |
| 6,568,177 Method for rapid catalyst heating | 84 | 2002 | |
| 6,779,337 Hydrogen fueled spark ignition engine | 9 | 2002 | |
| 6,895,747 Diesel aftertreatment systems | 7 | 2002 | |
| 6,862,879 Diesel aftertreatment system | 7 | 2002 | |
| 6,834,498 Diesel aftertreatment systems | 4 | 2002 | |
| 6,874,490 Method and system of adaptive learning for engine exhaust gas sensors | 14 | 2004 | |
| 6,955,155 Method for controlling transitions between operating modes of an engine for rapid heating of an emission control device | 7 | 2004 | |
| 7,059,112 Degradation detection method for an engine having a NOx sensor | 10 | 2004 | |
| 7,047,932 Method to improve fuel economy in lean burn engines with variable-displacement-like characteristics | 3 | 2004 | |
| 7,069,903 Idle speed control for lean burn engine with variable-displacement-like characteristic | 8 | 2004 | |
| 7,059,114 Hydrogen fueled spark ignition engine | 0 | 2004 | |
| 7,000,383 Diesel aftertreatment systems | 8 | 2004 | |
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| 6,272,849 Apparatus and method for heating an automotive catalyst to an emission reactive condition | 5 | 2000 | |
| 6,269,633 Emission control system | 49 | 2000 | |
| 6,539,704 Method for improved vehicle performance | 4 | 2000 | |
| 6,499,293 Method and system for reducing NOx tailpipe emissions of a lean-burn internal combustion engine | 9 | 2000 | |
| 6,487,849 Method and apparatus for controlling lean-burn engine based upon predicted performance impact and trap efficiency | 13 | 2000 | |
| 6,487,850 Method for improved engine control | 9 | 2000 | |
| 6,481,199 Control for improved vehicle performance | 10 | 2000 | |
| 6,477,832 Method for improved performance of a vehicle having an internal combustion engine | 13 | 2000 | |
| 6,438,944 Method and apparatus for optimizing purge fuel for purging emissions control device | 9 | 2000 | |
| 6,434,930 Method and apparatus for controlling lean operation of an internal combustion engine | 2 | 2000 | |
| 6,427,437 Method for improved performance of an engine emission control system | 6 | 2000 | |
| 6,374,597 Method and apparatus for accessing ability of lean NOx trap to store exhaust gas constituent | 13 | 2000 | |
| 6,360,530 Method and apparatus for measuring lean-burn engine emissions | 7 | 2000 | |
| 6,327,847 Method for improved performance of a vehicle | 13 | 2000 | |
| 6,308,515 Method and apparatus for accessing ability of lean NOx trap to store exhaust gas constituent | 15 | 2000 | |
| 6,308,697 Method for improved air-fuel ratio control in engines | 10 | 2000 | |
| 6,427,439 Method and system for NOx reduction | 43 | 2000 | |
| 6,389,803 Emission control for improved vehicle performance | 7 | 2000 | |
| 6,546,718 Method and system for reducing vehicle emissions using a sensor downstream of an emission control device | 5 | 2001 | |
| 6,539,706 Method and system for preconditioning an emission control device for operation about stoichiometry | 1 | 2001 | |
| 6,502,387 Method and system for controlling storage and release of exhaust gas constituents in an emission control device | 11 | 2001 | |
| 6,490,860 Open-loop method and system for controlling the storage and release cycles of an emission control device | 7 | 2001 | |
| 6,487,853 Method and system for reducing lean-burn vehicle emissions using a downstream reductant sensor | 7 | 2001 | |
| 6,467,259 Method and system for operating dual-exhaust engine | 44 | 2001 | |
| 6,463,733 Method and system for optimizing open-loop fill and purge times for an emission control device | 32 | 2001 | |
| 6,453,666 Method and system for reducing vehicle tailpipe emissions when operating lean | 3 | 2001 | |
| 6,490,856 Control for improved vehicle performance | 8 | 2002 | |
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| 6,651,597 Plasmatron having an air jacket and method for operating the same | 7 | 2002 | |
| 7,021,048 Combination emission abatement assembly and method of operating the same | 11 | 2002 | |
| 7,014,930 Apparatus and method for operating a fuel reformer to generate multiple reformate gases | 6 | 2002 | |
| 6,976,353 Apparatus and method for operating a fuel reformer to provide reformate gas to both a fuel cell and an emission abatement device | 14 | 2002 | |
| 6,758,035 Method and apparatus for purging SOX from a NOX trap | 12 | 2002 | |
| 6,702,991 Apparatus and method for reducing power consumption of a plasma fuel reformer | 8 | 2002 | |
| 6,715,452 Method and apparatus for shutting down a fuel reformer | 10 | 2002 | |
| 6,903,259 Thermoelectric device for use with fuel reformer and associated method | 6 | 2002 | |
| 6,851,398 Method and apparatus for controlling a fuel reformer by use of existing vehicle control signals | 20 | 2003 | |
| 6,959,542 Apparatus and method for operating a fuel reformer to regenerate a DPNR device | 14 | 2003 | |
| 7,285,247 Apparatus and method for operating a fuel reformer so as to purge soot therefrom | 2 | 2003 | |
| 7,244,281 Method and apparatus for trapping and purging soot from a fuel reformer | 3 | 2003 | |
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| 8,454,808 Hydrogen supplemental system for on-demand hydrogen generation for internal combustion engines | 0 | 2011 | |
| 8,449,733 Hydrogen supplemental system for on-demand hydrogen generation for internal combustion engines | 0 | 2011 | |
| 8,449,734 Hydrogen supplemental system for on-demand hydrogen generation for internal combustion engines | 0 | 2011 | |
| 8,449,735 Hydrogen supplemental system for on-demand hydrogen generation for internal combustion engines | 0 | 2011 | |
| 8,449,736 Hydrogen supplemental system for on-demand hydrogen generation for internal combustion engines | 0 | 2011 | |
| 8,449,754 Hydrogen supplemental system for on-demand hydrogen generation for internal combustion engines | 0 | 2011 | |
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| 6,276,132 Exhaust gas purifying system | 24 | 2000 | |
| 6,823,662 Exhaust gas purifying system | 20 | 2000 | |
| 6,557,342 Exhaust gas purifying system | 13 | 2001 | |
| 6,845,610 Exhaust gas purification apparatus and method | 18 | 2001 | |
| 6,708,484 Exhaust gas purifying system | 15 | 2002 | |
| 6,729,125 Exhaust gas purifying system | 19 | 2002 | |
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| 6,758,036 Method for sulfur protection of NOx adsorber | 17 | 2000 | |
| 6,655,130 System and controls for near zero cold start tailpipe emissions in internal combustion engines | 27 | 2000 | |
| 6,832,473 Method and system for regenerating NOx adsorbers and/or particulate filters | 54 | 2002 | |
| 7,093,428 Exhaust system and method of thermal management | 22 | 2004 | |
| 7,435,275 System and method of heating an exhaust treatment device | 2 | 2005 | |
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| 5,412,946 NOx decreasing apparatus for an internal combustion engine | 149 | 1992 | |
| 6,959,540 Exhaust gas purification device of internal combustion engine | 11 | 2004 | |
| 7,272,924 Exhaust gas purification device of internal combustion engine | 7 | 2005 | |
| 7,086,222 Exhaust gas purification device of internal combustion engine | 7 | 2005 | |
| 7,086,223 Exhaust gas purification device of internal combustion engine | 6 | 2005 | |
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| 6,036,827 Electrolyzer | 19 | 1997 | |
| 5,964,089 Diagnostics and control of an on board hydrogen generation and delivery system | 43 | 1997 | |
| 6,122,909 Catalytic reduction of emissions from internal combustion engines | 85 | 1998 | |
| 6,698,389 Electrolyzer for internal combustion engine | 15 | 2002 | |
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| 7,257,942 Apparatus for emissions control, systems, and methods | 3 | 2003 | |
| 7,278,259 Apparatus for emissions control, system, and methods | 5 | 2003 | |
| 7,607,289 Apparatus for emissions control, systems, and methods | 2 | 2007 | |
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| 6,041,594 Mixture delivery device for internal combustion engines | 36 | 1998 | |
| 7,594,393 Apparatus for introducing a reducing agent into the exhaust of an internal combustion engine | 7 | 2004 | |
| 7,975,472 Exhaust gas system for an internal combustion engine | 0 | 2007 | |
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| 6,293,096 Multiple stage aftertreatment system | 50 | 1999 | |
| 6,615,580 Integrated system for controlling diesel engine emissions | 32 | 2001 | |
| 6,718,757 Integrated method for controlling diesel engine emissions in CRT-LNT system | 24 | 2003 | |
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| 6,931,841 Process for the catalytic exhaust gas aftertreatment of engine combustion emissions | 0 | 2002 | |
| 7,003,946 Process for the catalytic exhaust gas aftertreatment of engine combustion emissions | 2 | 2004 | |
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| 6,543,216 Heating device for external combustion engine | 2 | 2002 | |
| 7,485,160 Hydrogen generating apparatus, hydrogen generating system and use thereof | 1 | 2003 | |
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| 6,327,851 Process for controlled injection of hydrocarbons into an exhaust line of an internal-combustion engine | 5 | 1999 | |
| 6,508,057 Process and device intended for nitrogen oxides elimination in an exhaust line of an internal-combustion engine | 25 | 1999 | |
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| 5,474,745 Catalytic converter for purifying exhaust gas | 7 | 1994 | |
| 5,543,124 Process for reducing nitrogen oxides | 33 | 1994 | |
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| 6,427,639 Method and apparatus for warming intake air to an internal combustion engine | 16 | 1998 | |
| RE39720 Catalytic reduction of emissions from internal combustion engines | 2 | 2001 | |
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| 6,560,958 Emission abatement system | 57 | 1999 | |
| 6,718,753 Emission abatement system utilizing particulate traps | 18 | 2002 | |
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| 7,152,394 System and method for reducing nitrogen oxides in the exhaust of an internal combustion engine | 1 | 2002 | |
| 7,051,518 Internal combustion engine fuel supply system | 2 | 2005 | |
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| 5,813,222 Method and apparatus for heating a catalytic converter to reduce emissions | 41 | 1994 | |
| 5,953,908 Method and apparatus for heating a catalytic converter to reduce emissions | 18 | 1997 | |
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| 6,236,930 Sensor output precision enhancement in an automotive control system | 0 | 1999 | |
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| 6,739,125 Internal combustion engine with SCR and integrated ammonia production | 50 | 2002 | |
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| 8,181,445 Device and method for exhaust gas aftertreatment | 0 | 2004 | |
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| 5,921,076 Process and apparatus for reducing nitrogen oxides in engine emissions | 64 | 1997 | |
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| 7,776,280 Method and apparatus for selective catalytic reduction of NOx | 2 | 2005 | |
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| 6,981,367 Hydrogen and oxygen generation from a water vapor containing exhaust | 4 | 2003 | |
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| 6,755,017 Device for purifying exhaust gas of an internal combustion engine | 6 | 2001 | |
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| 8,281,577 Exhaust gas purification system and exhaust gas purification method | 0 | 2008 | |
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| 6,722,124 Catalytic converter | 22 | 2002 | |
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| 7,288,135 Solid multicomponent mixed proton and electron conducting membrane | 1 | 2002 | |
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| 7,601,316 Method of reducing NOx and particulates from internal combustion engines | 0 | 2003 | |
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| 7,562,521 SCR muffler | 0 | 2005 | |
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| 7,767,163 Exhaust treatment devices | 2 | 2004 | |
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| 7,249,598 Hydrogen augmented diesel crankcase ventilation | 3 | 2006 | |
| 7,571,719 Hydrogen augmented diesel crankcase ventilation | 0 | 2007 | |
| 8,163,142 Hydrogen system for internal combustion engine | 0 | 2009 | |
| 8,464,667 Hydrogen system for internal combustion engine | 0 | 2010 | |
Maintenance Fees
| Fee | Large entity fee | small entity fee | micro entity fee | due date |
|---|
| Fee | Large entity fee | small entity fee | micro entity fee |
|---|---|---|---|
| Surcharge after expiration - Late payment is unavoidable | $700.00 | $350.00 | $175.00 |
| Surcharge after expiration - Late payment is unintentional | $1,640.00 | $820.00 | $410.00 |