Sensor and method for accurately measuring concentrations of oxide compounds in gas mixtures

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United States of America Patent

PATENT NO 5397442
SERIAL NO

08208449

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Abstract

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Sensors (10, 40) accurately measure the concentration of an oxide compound, such as nitrogen oxide NO.sub.x, in a gas mixture (11) which can include oxygen O.sub.2. The sensors (10, 40) each comprise a chamber (12, 42) adapted to receive the gas mixture (11) as well as first and second electrochemical cells (16, 17) for consuming oxygen and/or the oxide compound in the chamber (12, 42). The first electrochemical cell (16) comprises a first internal electrode (16a) inside the chamber (12, 42), a first external electrode (16b) outside the chamber (12, 42), and a first electrolyte body (14') therebetween. The second electrochemical cell (17) comprises a second internal electrode (17a) inside the chamber (12, 42), a second external electrode (17b) outside the chamber (12, 42), and a second electrolyte body (14') therebetween. The first and second electrolyte bodies (14', 14') are permeable to oxygen ions. Significantly, the first and second internal electrodes (16a, 17a) are metal oxides having a perovskite lattice structure, which generally exhibit high relative selectivity between oxide compounds, including NO.sub.x, and O.sub.2. The electrical characteristics of the first and second electrochemical cells (16, 17) are manipulated and/or monitored in order to determine the concentration of NO.sub.x within the chambers (12, 42) and the gas mixture (11).

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Patent Owner(s)

Patent OwnerAddress
GAS TECHNOLOGY INSTITUTE1700 SOUTH MOUNT PROSPECT ROAD DES PLAINES IL US 60018

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Wachsman, Eric D Palo Alto, CA 45 478

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