Chargeable lithium electrochemical cell and method of manufacting it
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United States of America Patent
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Oct 1, 1996
Grant Date -
N/A
app pub date -
Jul 8, 1994
filing date -
Jul 9, 1993
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Expired
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Abstract
The present invention consists in a rechargeable cell having an anode made from materials in which lithium can be inserted, a cathode and an electrolyte constituted by a solution of a lithium salt in a non-aqueous solvent. The material of said cathode includes at least one substance which is a yellow-green single-phase oxide of lithium and manganese with an orthorhombic crystal structure with the following lattice parameters: a=0.459.+-.0.004 nm, b=0.577.+-.0.004 nm and c=0.281.+-.0.003 nm and containing lithium ions in a molar ratio Li/Mn such that 0.85.ltoreq.Li/Mn.ltoreq.1.10. After a first charge said substance is discharged in two stages of which the higher is at a mean voltage greater than 3.5 volts relative to the lithium.
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