Method of treating shale and clay in hydrocarbon formation drilling
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United States of America Patent
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Mar 4, 1997
Issued Date -
N/A
app pub date -
Mar 4, 1996
filing date -
Nov 19, 1993
priority date (Note) -
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Abstract
Swelling and migration of subterranean clay is inhibited during drilling for and stimulation of the production of hydrocarbon fluids, and preparation therefor, by treating said formations with a copolymer of about 5% to about 50% of an anionic monomer such as acrylic acid, methacrylic acid, or 2-acrylamido-2-methyl propane sulfonic acid and the balance a cationic monomer selected from dimethyl diallyl ammonium chloride, or acryloxy or methacryloxy ethyl, propyl or 3-methyl butyl trimethyl ammonium chlorides or methosulfates. Permeability damage to the formation is reduced in the presence of the copolymer; it is particularly effective in spite of the presence of a foaming agent.
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