Amine monomers and their use in preparing interfacially synthesized membranes for reverse osmosis and nanofiltration
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United States of America Patent
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Jul 13, 1999
Grant Date -
N/A
app pub date -
Oct 7, 1997
filing date -
Oct 7, 1997
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Abstract
Water permeable reverse osmosis membranes are prepared by interfacially polymerizing on a microporous support an essentially monomeric polyamine reactant having at least two amine functional groups per reactant molecule, and an essentially monomeric amine-reactive polyfunctional aromatic or cycloaliphatic acyl halide having on the average at least about 2 acyl halide groups per reactant molecule. The polymerization is optionally carried out in the presence of a monomeric amine salt, which increases the flux rate of the resulting membrane. Preferred polyamine compounds of the generic formula, which are novel per se, include 3,5-diaminobenzoyl piperazine, 4-aminobenzoyl piperazine, 3-aminobenzoyl piperazine, isophthaloyl piperazine, and terephthaloyl piperazine.
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