Acid catalyzed polymerization

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United States of America Patent

PATENT NO 5948874
SERIAL NO

09065974

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Abstract

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The present invention is an improvement in a free radical bulk polymerization process for preparing a high molecular weight polymer from a vinyl aromatic monomer characterized in that the polymerization is conducted in the presence of an acid catalyst having a pKa at 25.degree. C. of less than 2, or salt thereof, wherein the improvement comprises dispersing the acid catalyst, or salt thereof, in a (meth)acrylic acid or ester thereof, prior to contact with the vinyl aromatic monomer. The (meth)acrylic acid or ester allows the acid catalyst to be dispersed within the vinyl aromatic monomer without causing cationic polymerization. The acid catalyst, or salt thereof, catalyzes the free radical polymerization reaction such that high molecular weight polymers are produced in reasonable reaction times.

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Patent Owner(s)

Patent OwnerAddress
DOW CHEMICAL COMPANY THE2030 DOW CENTRE ABBOTT ROAD MIDLAND MICHIGAN 48640 UNITED STATES OF AMERICA

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Pike, William C Midland, MI 12 78
Priddy, Duane B Midland, MI 43 358

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