Multiple-doped oxide cathode material for secondary lithium and lithium-ion batteries

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United States of America Patent

PATENT NO 6040089
SERIAL NO

09031849

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Abstract

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The present invention provides a positive electrode material for lithium and lithium-ion secondary cells which exhibits good cycleability, reversible specific capacity, and structural stability. The positive electrode material comprises a lithium multi metal oxide having a spinel structure and described by the general formula: Li.sub.1+X Mn.sub.2-Y M.sub.m.sbsb.1.sup.1 M.sub.m.sbsb.2.sup.2 . . . M.sub.m.sbsb.k.sup.k O.sub.4+Z wherein M.sup.1, M.sup.2, . . . M.sup.k are at least two cations different than lithium or manganese, selected from the group consisting of alkaline earth metals, transition metals, B, Al, Si, Ga and Ge; X, Y, m.sub.1,m.sub.2, . . . m.sub.k are numbers between 0 and 0.2; m.sub.1, m.sub.2 and Y are greater than 0; Z is a number between -0.1 and 0.2; and wherein the metals M.sup.1, M.sup.2, . . . M.sup.k and the corresponding values m.sub.1, m.sub.2, . . . m.sub.k satisfy the following equation and inequality: ##EQU1## wherein V.sub.1, V.sub.2, . . . V.sub.k are the corresponding valence states of the cations M.sup.1, M.sup.2, . . . M.sup.k.

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Patent Owner(s)

  • FMC CORPORATION

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Barnette, Wayne Bessemer City, NC 1 42
Faulkner, Titus Gastonia, NC 19 269
Gao, Yuan Ocean, NJ 408 2246
Manev, Vesselin Gastonia, NC 12 214

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