Production of electrolytic copper from dilute solutions contaminated by other metals

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United States of America Patent

PATENT NO 6086744
SERIAL NO

09135255

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Abstract

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The copper is selectively precipitated in the form of a sulfide from the solutions containing it, according to the reaction: Cu.sup.2+ +S.sup.2- .fwdarw.CuS The precipitated solid, constituted by copper sulfide, is filtered, washed and then leached with a solution of ferric fluoborate and fluoboric acid, which dissolves the copper as a fluoborate while forming elemental sulfur, according to the reaction: CuS+2Fe(BF.sub.4).sub.3 .fwdarw.Cu(BF.sub.4).sub.2+2Fe(BF.sub.4).sub.2 +S.sup.o After filtering off the sulfur, the copper fluoborate solution is subjected to an electrolysis in a diaphragm cell, obtaining a deposit of pure copper at the cathode and a regenerated solution of ferric fluoborate at the anode, which is utilized to leach further copper sulfide.

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Patent Owner(s)

Patent OwnerAddress
ECOCHEM AKTIENGESELLSCHAFTTRIESEN 9495

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Zoppi, Gianni Dino Di Sonvico, CH 8 31

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