Method for the preparation of copolymers of ethylene/norbornene-type monomers with nickel catalysts

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United States of America Patent

PATENT NO 6197984
SERIAL NO

09305942

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Abstract

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A method of preparing amorphous copolymers of ethylene and at least one norbornene (NB)-type comonomer is disclosed. These polymers may be random or alternating depending on the choice of catalyst and/or the relative ratio of the monomers used. This method comprises polymerizing said monomers in a diluent or in bulk in the presence of a neutral nickel catalyst which may be represented by the formula ##STR1## wherein Y may be a saturated or unsaturated hydrocarbyl chain, X may be oxygen or sulfur, E may be phosphorus, arsenic, antimony, oxygen or nitrogen, R and R' independently each is hydrogen or a hydrocarbyl group, L is a ligand containing a heteroatom P, N or O or L and R together with L may form part of a chelating structure in which case L is an ethylenic double bond.

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Patent Owner(s)

Patent OwnerAddress
SUMITOMO BAKELITE CO LTD5-8 HIGASHI-SHINAGAWA 2-CHOME SHINAGAWA-KU TOKYO 1400002 ?1400002

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Bagdasaryan, Andrey Khristoforovich Moscow, RU 2 30
Bykov, Viktor Ivanovich Moscow, RU 2 30
Finkelshtein, Eugeny Shmerovich Moscow, RU 2 30
Makovetsky, Kiryll Lvovich Moscow, RU 2 30
Rhodes, Larry Funderburk Silver Lake, OH 10 130

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