Preparation of fluorine modified, low haze, titanium dioxide films

Number of patents in Portfolio can not be more than 2000

United States of America Patent

PATENT NO 6268019
SERIAL NO

09315193

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Abstract

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The present invention concerns the deposition of fluorine modified, titanium dioxide films (TiO.sub.2) onto hot glass by atmospheric pressure chemical vapor deposition (APCVD) using TiCl.sub.4 vapor. The invention is also suitable for depositing other metallic oxide films from their metallic halides such as SnCl.sub.4, GeCl.sub.4, and VCl.sub.4. The present invention provides a process that deposits a novel, fluorine modified, titanium dioxide film (TiO.sub.2) onto hot glass by atmospheric pressure chemical vapor deposition using TiCl.sub.4 vapor. The process uses injection of TiCl.sub.4 into a hot, nonoxygen containing carrier gas and blends the carrier gas and TiCl.sub.4 vapor with an oxygen containing gas stream containing a haze reducing quantity of a fluorine containing compound before contacting a surface of hot glass with the blended mixture. The process is capable of depositing a fluorine modified, TiO.sub.2 film at deposition rates exceeding 900 .ANG. per second. The crystalline phase of the fluorine modified film is essentially anatase. The film has a haze of less then 1% and a refractive index of greater than or equal to about 2.48. Also provided is an apparatus for practicing the process and a novel coated glass.

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Patent Owner(s)

Patent OwnerAddress
ATOFINA CHEMICALS INC A CORP OF PENNSYLVANIA2000 MARKET STREET PHILADELPHIA PA 19103

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Florczak, Glenn P East Brunswick, NJ 5 40

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