US Patent No: 6,280,864

Number of patents in Portfolio can not be more than 2000

Control system for providing hydrogen for use with fuel cells

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Importance

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Abstract

Hydrogen generation and fuel cell operation are integrated through the use of a low-cost hydrogen generation zone which comprises a pre-reforming zone, a partial oxidation zone, a reforming zone, and a water gas shift zone. Anode waste gas from the fuel cell is burned to provide heat to pre-reform the feed to the hydrogen generation zone while the burner exit temperature and the reforming zone exit temperatures are controlled using a simplified control system to eliminate thermal cycling in the hydrogenation zone. This simplified control of the hot side temperatures in the hydrogen generation zone below about 700.degree. C. combined with use of the pre-reforming zone, surprisingly permits the use of carbon steel and/or stainless steel for construction of the hydrogenation zone while providing an efficient system which does not require external fuel and offers a high degree of feedstock flexibility at low cost.

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First Claim

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Patent Owner(s)

Patent OwnerAddressTotal Patents
HYRADIX, INC.DES PLAINES, IL13

International Classification(s)

Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Doshi, Kishore J Lake Zurick, IL 21 519
Senetar, John J Naperville, IL 41 316
Towler, Gavin P Barrington, IL 97 496
Vanden, Bussche Kurt M Lake in the Hills, IL 87 382

Cited Art

Patent Info (Count) # Cites Year
 
INTERNATIONAL FUEL CELLS CORPORATION (2)
4,943,493 Fuel cell power plant 33 1989
5,733,347 Compact fuel gas reformer assemblage 42 1995
 
LG FUEL CELL SYSTEMS INC. (2)
5,486,428 Solid oxide fuel cell stack 40 1995
5,595,833 Solid oxide fuel cell stack 44 1995
 
AIR PRODUCTS AND CHEMICALS, INC. (1)
4,869,894 Hydrogen generation and recovery 44 1987
 
ENERGY RESEARCH CORPORATION (1)
4,716,023 Composite partial oxidizer and reformer 24 1986
 
ENGELHARD CORPORATION (1)
4,522,894 Fuel cell electric power production 139 1984
 
HITACHI, LTD. (1)
4,861,348 Fuel reforming apparatus 21 1987
 
INTERNATIONAL FUEL CELLS, LLC (1)
6,120,923 Steam producing hydrocarbon fueled power plant employing a PEM fuel cell 61 1998
 
ISHIKAWAJIMA-HARIMA HEAVY INDUSTRIES CO., LTD. (1)
5,609,834 Plate reformer 36 1995
 
JOHNSON MATTHEY PUBLIC LIMITED COMPANY (1)
4,863,712 Catalysts for reforming hydrocarbon feedstocks 37 1988
 
KABUSHIKIKAISHA EQUOS RESEARCH (1)
5,648,182 Fuel cell power generation system 38 1995
 
KINETICS TECHNOLOGY INTERNATIONAL CORPORATION (1)
4,692,306 Catalytic reaction apparatus 53 1986
 
LOCKHEED IDAHO TECHNOLOGIES COMPANY (1)
5,641,585 Miniature ceramic fuel cell 78 1995
 
M.W. KELLOGG COMPANY, THE (1)
4,479,925 Preparation of ammonia synthesis gas 39 1982
 
MARATHON OIL COMPANY (1)
5,861,441 Combusting a hydrocarbon gas to produce a reformed gas 42 1997
 
NGK INSULATORS, LTD. (1)
5,741,474 Process for production of high-purity hydrogen 84 1995
 
STANDARD OIL COMPANY (INDIANA) (1)
5,651,833 Waste concentration and destruction process 8 1996
 
STONE & WEBSTER PROCESS TECHNOLOGY, INC. (1)
5,181,937 Apparatus for production of synthesis gas using convective reforming 21 1991
 
THE BRITISH PETROLEUM COMPANY P.L.C. (1)
4,925,456 Process and apparatus for the production of synthesis gas 18 1987
 
TOKYO ELECTRIC POWER COMPANY, INCORPORATED, THE (1)
5,226,928 Reforming apparatus for hydrocarbon 55 1990
 
UOP LLC (1)
4,691,071 Dehydrogenation of dehydrogenatable hydrocarbons 15 1986
 
WELLMAN DEFENCE LIMITED (1)
5,401,589 Application of fuel cells to power generation systems 197 1993
 
WESTINGHOUSE ELECTRIC CORP. (1)
5,143,800 Electrochemical cell apparatus having combusted exhaust gas heat exchange and valving to control the reformable feed fuel composition 74 1990
 
ZTEK CORPORATION (1)
5,858,314 Thermally enhanced compact reformer 120 1996

Patent Citation Ranking

Forward Cites

Patent Info (Count) # Cites Year
 
INTELLIGENT ENERGY, INC. (5)
7,875,089 Ammonia-based hydrogen generation apparatus and method for using same 0 2002
7,811,529 Hydrogen generation apparatus and method for using same 1 2002
7,922,781 Hydrogen generation apparatus and method for using same 1 2005
7,867,300 Ammonia-based hydrogen generation apparatus and method for using same 0 2005
7,527,661 Compact devices for generating pure hydrogen 1 2005
 
AIR PRODUCTS AND CHEMICALS, INC. (2)
7,449,167 Catalyst and process for improving the adiabatic steam-reforming of natural gas 2 2004
7,622,058 Catalyst for improving the adiabatic steam reforming of natural gas 1 2008
 
GM GLOBAL TECHNOLOGY OPERATIONS LLC (2)
7,824,455 High activity water gas shift catalysts based on platinum group metals and cerium-containing oxides 0 2003
7,238,333 High activity water gas shift catalysts with no methane formation 1 2004
 
NISSAN MOTOR CO., LTD. (2)
6,706,434 Fuel cell system 1 2001
6,582,841 Fuel cell system and method of controlling the same 8 2001
 
PRESTONE PRODUCTS CORPORATION (2)
7,481,948 Heat transfer compositions with high electrical resistance for fuel cell assemblies 2 2003
7,608,198 Heat transfer compositions with high electrical resistance for fuel cell assemblies 0 2008
 
ULTRACELL ACQUISITION COMPANY, L.L.C. (2)
7,807,129 Portable fuel processor 0 2007
7,807,130 Fuel processor dewar and methods 1 2007
 
UOP LLC (2)
7,740,751 Process for heating a stream for a hydrocarbon conversion process 0 2006
8,282,814 Fired heater for a hydrocarbon conversion process 0 2009
 
APPLIED RESEARCH ASSOCIATES, INC. (1)
7,318,845 Compact distillates fuel processor with effective sulfur removal process 1 2003
 
BAYERISCHE MOTOREN WERKE AKTIENGESELLSCHAFT (1)
6,562,496 Integrated solid oxide fuel cell mechanization and method of using for transportation industry applications 54 2001
 
BP CORPORATION NORTH AMERICA INC. (1)
6,749,829 Hydrogen to steam reforming of natural gas to synthesis gas 4 2002
 
DCNS SA (1)
8,034,500 Systems and methods for starting and operating fuel cell systems in subfreezing temperatures 0 2007
 
DELPHI TECHNOLOGIES, INC. (1)
6,627,339 Fuel cell stack integrated with a waste energy recovery system 31 2001
 
HYRADIX, INC. (1)
8,282,907 Hydrogen generation processes and apparatus and control system 0 2007
 
KOREA INSTITUTE OF ENERGY RESEARCH (1)
7,247,258 Compact partial oxidation reactor assemblage with fast start-up capability 2 2003
 
PANASONIC CORPORATION (1)
8,293,416 Fuel cell system 0 2007
 
PLUG POWER INC. (1)
6,551,733 Controlling the temperature at which fuel cell exhaust is oxidized 3 2000
 
TEXACO INC. (1)
8,260,464 Architectural hierarchy of control for a fuel processor 0 2007
 
UMICORE AG & CO. KG (1)
7,147,947 Selective carbon monoxide oxidation catalyst, method of making the same and systems using the same 2 2002
 
UTC FUEL CELLS, LLC (1)
6,828,048 Shut-down procedure for fuel cell fuel processing system 11 2001
 
OTHER [CHECK PATENT PROFILE FOR ASSIGNMENT INFORMATION] (2)
6,620,537 Hydrocarbon fueled hydrogen fuel generator system and apparatus in combination with hydrogen fuel cells 9 2001
8,172,913 Array of planar membrane modules for producing hydrogen 0 2009

Maintenance Fees

Fee Large entity fee small entity fee micro entity fee due date
11.5 Year Payment $7400.00 $3700.00 $1850.00 Feb 28, 2013
Fee Large entity fee small entity fee micro entity fee
Surcharge - 11.5 year - Late payment within 6 months $160.00 $80.00 $40.00
Surcharge after expiration - Late payment is unavoidable $700.00 $350.00 $175.00
Surcharge after expiration - Late payment is unintentional $1,640.00 $820.00 $410.00