Production of nitriles via hydrocyanation of ethylenically unsaturated organic compounds

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United States of America Patent

PATENT NO 6469194
SERIAL NO

09886288

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Abstract

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Ethylenically unsaturated organic compounds, for example diolefins, olefinic nitriles and monoolefins, are noncontaminatingly hydrocyanated into corresponding nitriles by (a) reacting such ethylenically unsaturated organic compounds with hydrogen cyanide in the presence of an aqueous solution containing a catalytically effective amount of a catalyst which comprises at least one nickel compound and at least one water-soluble phosphine, (b) thereafter separating the organic phase from the aqueous phase which result, the separated aqueous phase comprising a solid phase formed during hydrocyanation, and (c) thence treating the separated aqueous phase, or a solid phase removed therefrom, with hydrogen cyanide to thus at least partially dissolve said solid phase contained therein or removed therefrom.

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Patent Owner(s)

Patent OwnerAddress
RHODIA FIBER AND RESIN INTERMEDIATES25 QUAI PAUL DOUMER F-92408 COURBEVOIE CEDEX

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Burattin, Paolo Lyons, FR 13 94
Coqueret, Pierre Francheville, FR 6 25
Huser, Marc Villeurbanne, FR 14 90

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