Method for the preparation of core-shell morphologies from polybutadiene-polystyrene graft copolymers

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United States of America Patent

PATENT NO 6489378
SERIAL NO

09661611

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High impact polystyrene having a predominant core-shell morphology is made by polymerizing styrene in the presence of polybutadiene using toluene as a solvent. The thermoplastic polymer composition is characterized by a continuous phase of polystyrene containing dispersed graft copolymer particles having a core-shell structure with a polystyrene core occluded inside a polybutadiene shell. The styrene is desirably batch polymerized using styrene/toluene mixtures of about 70:30 by weight in the presence of from about 9 to about 15 weight percent polybutadiene while flashing off the toluene solvent.

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FINA TECHNOLOGY INCP O BOX 674412 HOUSTON TX 77267-4412

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Inventor Name Address # of filed Patents Total Citations
Kelly, Lu Ann Friendswood, TX 16 129
Sosa, Jose M Deer Park, TX 65 328

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