Process for producing vinyl acetate resin emulsion and water-based adhesive
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United States of America Patent
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Dec 17, 2002
Grant Date -
N/A
app pub date -
Oct 3, 2000
filing date -
Feb 18, 1999
priority date (Note) -
Expired
status (Latency Note)
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Abstract
A process of the invention produces a vinyl acetate polymer based emulsion by seed polymerization of vinyl acetate in an ethylene-vinyl acetate copolymer based emulsion. This process includes a step of performing seed polymerization while adding vinyl acetate to a system, and, prior to or subsequent to the step, a step of adding a polymerizable unsaturated monomer other than vinyl acetate to the system. The amount of the polymerizable unsaturated monomer other than vinyl acetate is, for example, about 0.05 to 10 parts by weight relative to 100 parts by weight of vinyl acetate. At least one monomer selected from acrylic esters, methacrylic esters, vinyl esters, and vinyl ethers can be used as the polymerizable unsaturated monomer other than vinyl acetate. The invented process can produce a vinyl acetate polymer based emulsion which has satisfactory low-temperature film-forming property and adhesive strength, even containing no plasticizer, and which can exhibit a high adhesive strength even when cured at low temperatures.
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