Oil-resistant rubber modified polystyrene composition
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United States of America Patent
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Dec 2, 2003
Grant Date -
Jun 20, 2002
app pub date -
Oct 24, 2001
filing date -
Oct 24, 2000
priority date (Note) -
Expired
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Abstract
An oil resistant rubber modified polystyrene composition comprises polybutadiene rubber particles having an average volume particle diameter of 6 to 13 .mu.m dispersed in polystyrene. The oil resistant rubber modified polystyrene of the present invention has a gel content of 25 to 35% by weight, a degree of swelling of 13 to 22, a residual volatile content of 2000 ppm or less, and a total amount of dimer and trimer of 8000 ppm or less. The oil resistant rubber modified polystyrene composition may be prepared by polymerizing styrene in the presence of polybutadiene rubber, foaming a solution of the rubber modified polystyrene under a reduced pressure of 3 to 40 mm Hg, heating the solution in a tubular heater to a temperature of 190 to 230.degree. C., and then flushing the heated solution into a gas-liquid separator to devolatilize an unreacted monomer and a solvent therefrom.
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