Plasma processes for depositing low dielectric constant films

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United States of America Patent

PATENT NO 6660656
APP PUB NO 20020045361A1
SERIAL NO

09957551

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Abstract

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A method and apparatus for depositing a low dielectric constant film by reaction of an organosilicon compound and an oxidizing gas at a constant RF power level from about 10W to about 200W or a pulsed RF power level from about 20W to about 500W. Dissociation of the oxidizing gas can be increased prior to mixing with the organosilicon compound, preferably within a separate microwave chamber, to assist in controlling the carbon content of the deposited film. The oxidized organosilane or organosiloxane film has good barrier properties for use as a liner or cap layer adjacent other dielectric layers. The oxidized organosilane or organosiloxane film may also be used as an etch stop and an intermetal dielectric layer for fabricating dual damascene structures. The oxidized organosilane or organosiloxane films also provide excellent adhesion between different dielectric layers. A preferred oxidized organosilane film is produced by reaction of methylsilane, CH.sub.3 SiH.sub.3, dimethylsilane, (CH.sub.3).sub.2 SiH.sub.2, or 1,1,3,3-tetramethyl-disiloxane, (CH.sub.3).sub.2 --SiH--O--SiH--(CH.sub.3).sub.2, and nitrous oxide, N.sub.2 O, at a constant RF power level from about 10W to about 150W, or a pulsed RF power level from about 20W to about 250W during 10% to 30% of the duty cycle.

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Patent Owner(s)

Patent OwnerAddress
APPLIED MATERIALS INC3050 BOWERS AVENUE SANTA CLARA CA 95054

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Barnes, Michael San Ramon, CA 149 6685
Cheung, David Foster City, CA 153 7553
Ishikawa, Tetsuya Santa Clara, CA 358 14699
Jeng, Shin-Puu Hsinchu, TW 851 18082
Liu, Kuo-Wei Campbell, CA 14 1098
Lu, Yung-Cheng San Jose, CA 179 2493
Mandal, Robert P Saratoga, CA 37 2317
Moghadam, Farhad Los Gatos, CA 40 2414
Poon, Tze Wing San Francisco, CA 14 1323
Willecke, Ralf B Santa Clara, CA 18 1252
Yau, Wai-Fan Mountain View, CA 74 6440

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