Moisture-induced poly(ethylene oxide) gel, method of making same and articles using same
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United States of America Patent
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Sep 14, 2004
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N/A
app pub date -
May 26, 2000
filing date -
May 26, 2000
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Expired
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Abstract
A method for making modified poly(ethylene oxide) by graft polymerizing thereto organic monomers containing a trialkoxy silane functional group or a moiety that reacts with water to form a silanol group, such as methacryloxypropyl trimethoxy silane, onto the poly(ethylene oxide) is disclosed. The graft polymerization is accomplished by mixing the poly(ethylene oxide), the silane-containing monomer(s) and an initiator and applying heat. Preferably, the method is a reactive-extrusion process. After graft polymerization, the modified poly(ethylene oxide) may be exposed or subjected to relatively high moisture conditions, thereby causing crosslinking and formation of a structure that is capable of absorbing relatively large amounts of saline. The resulting modified poly(ethylene oxide) has improved properties over articles similarly processed from unmodified poly(ethylene oxide).
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