Chiral catalyst, process for preparing the same and its use in the oxidate coupling of naphthols

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United States of America Patent

PATENT NO 7151070
APP PUB NO 20050256345A1
SERIAL NO

10518118

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Abstract

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The compound of this invention is a useful catalyst for the oxidative coupling of naphthol. Its originality lies in that it is a novel vanadium complex of Schiff's base formed by a chiral amino acid and a formyl biphenol or its derivative. Its axis chirality is induced to form by the chiral amino acid. It has the general formula: ##STR00001## where R represents a benzyl, an isopropyl, an isobutyl or a tertiary butyl and the configuration of the amino acid is R or S. The compound can catalyze oxidative coupling of naphthol or its derivative to form binaphthol or its derivatives with a high optical purity.

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Patent Owner(s)

Patent OwnerAddress
CHENGDU INSTITUTE OF ORGANIC CHEMISTRY CHINESE ACADEMY OF SCIENCES610041 NO FOUR SOUTH RENMIN ROAD SICHUAN CHENGDU PROVINCE NINE CHENGDU CITY SICHUAN PROVINCE 610041

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Gong, Liuzhu Sichuan, CN 1 1
Jiang, Yaozhong Sichuan, CN 1 1
Liu, Quanzhong Sichuan, CN 2 2
Luo, Zhibin Sichuan, CN 2 1
Mi, Aiqiao Sichuan, CN 2 24

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