
US Patent No: 7,226,541
Number of patents in Portfolio can not be more than 2000
Membrane polymer compositions
Stats
-
Jun 5, 2007
Issued date -
Dec 16, 2003
filing date -
10/738,628
serial no -
In Force
status
Importance
Abstract
The invention relates to a terpolymer of tetrafluoroethylene (TFE) monomer, polyvinylidene fluoride (PVDF) monomer and hexafluoropropylene (HFP) monomer for forming an ultrafiltration or microfiltration membrane, method of forming said membranes, and to the ultrafiltration or microfiltration membranes themselves. The invention also relates to a method of forming a polymeric ultrafiltration or microfiltration membrane including preparing a leachant resistant membrane dope which incorporates a leachable pore forming agent, casting a membrane from the dope and leaching the pore forming agent from the membrane. The invention also relates to a method of preparing a polymeric ultrafiltration or microfiltration membrane of improved structure including the step of adding a nucleating agent to the membrane dope before casting.
First Claim
Related Publications
International Classification(s)
- [Classification Symbol]
- [Patents Count]
Cited Art
| Patent Info | (Count) | # Cites | Year |
|---|---|---|---|
|
|
|||
| 5,643,455 Concentration of solids in a suspension using hollow fibre membranes | 90 | 1995 | |
| 5,918,264 Fiber monitoring system | 42 | 1995 | |
| 6,159,373 Cleaning of hollow fibre membranes | 41 | 1997 | |
| 6,077,435 Filtration monitoring and control system | 71 | 1998 | |
| 6,156,200 Gas-scrubbed hollow fiber membrane module | 87 | 1998 | |
| 6,254,773 Microporous membrane filtration assembly | 39 | 1999 | |
| 6,555,005 Scouring method | 61 | 1999 | |
| 6,202,475 Predicting logarithmic reduction values | 42 | 1999 | |
| D478913 Manifold header | 32 | 2000 | |
| D462699 Manifold header cap | 39 | 2000 | |
| 6,524,481 Apparatus and method for cleaning membrane filtration modules | 55 | 2001 | |
| 6,641,733 Apparatus and method for cleaning membrane filtration modules | 41 | 2002 | |
| 6,884,350 Modified membranes | 33 | 2003 | |
|
|
|||
| 5,227,063 Tubular membrane module | 45 | 1990 | |
| 5,104,535 Frameless array of hollow fiber membranes and module containing a stack of arrays | 53 | 1990 | |
| 5,182,019 Cartridge of hybrid frameless arrays of hollow fiber membranes and module containing an assembly of cartridges | 56 | 1992 | |
| 5,248,424 Frameless array of hollow fiber membranes and method of maintaining clean fiber surfaces while filtering a substrate to withdraw a permeate | 139 | 1992 | |
| 5,403,479 In situ cleaning system for fouled membranes | 84 | 1993 | |
| 5,958,243 Apparatus and method for membrane filtration with enhanced net flux | 51 | 1997 | |
| 5,910,250 Baffle for conversion of fine bubbles to coarse while filtering with a vertical skein of hollow fibers | 87 | 1997 | |
| 5,914,039 Filtration membrane with calcined .alpha.-alumina particles therein | 59 | 1997 | |
| 5,944,997 System for maintaining a clean skein of hollow fibers while filtering suspended solids | 103 | 1998 | |
| 6,045,698 Method for cleaning a filtration installation of the type with immersed membranes | 61 | 1998 | |
| 6,024,872 Method of making a dope comprising hydrophilized PVDF and .alpha.-alumina, and a membrane made therefrom | 53 | 1999 | |
| 6,214,231 System for operation of multiple membrane filtration assemblies | 60 | 1999 | |
| 6,645,374 Membrane module for gas transfer and membrane supported biofilm process | 47 | 2003 | |
|
|
|||
| 5,639,373 Vertical skein of hollow fiber membranes and method of maintaining clean fiber surfaces while filtering a substrate to withdraw a permeate | 128 | 1995 | |
| 5,783,083 Vertical cylindrical skein of hollow fiber membranes and method of maintaining clean fiber surfaces | 119 | 1996 | |
| 6,042,677 Potted header for hollow fiber membranes and method for making it | 70 | 1999 | |
| RE37549 Vertical skein of hollow fiber membranes and method of maintaining clean fiber surfaces while filtering a substrate to withdraw a permeate | 63 | 1999 | |
| 6,354,444 Hollow fiber membrane and braided tubular support therefor | 61 | 1999 | |
| 6,193,890 System for maintaining a clean skein of hollow fibers while filtering suspended solids | 83 | 1999 | |
| 6,375,848 Water filtration using immersed membranes | 50 | 1999 | |
| 6,245,239 Cyclic aeration system for submerged membrane modules | 61 | 2000 | |
| 6,325,928 Immersed membrane element and module | 60 | 2000 | |
| 6,294,039 Potted header for hollow fiber membranes | 54 | 2000 | |
| 6,893,568 Immersed membrane filtration system and overflow process | 36 | 2000 | |
| 6,550,747 Cyclic aeration system for submerged membrane modules | 48 | 2001 | |
| 6,620,319 Apparatus for withdrawing permeate using an immersed vertical skein of hollow fibre membranes | 50 | 2001 | |
|
|
|||
| 4,340,479 Process for preparing hydrophilic polyamide membrane filter media and product | 202 | 1980 | |
| 4,431,545 Microporous filter system and process | 80 | 1982 | |
| 4,609,465 Filter cartridge with a connector seal | 109 | 1984 | |
| 4,702,840 Charge modified polyamide membrane | 71 | 1986 | |
| 5,417,101 Method and apparatus for testing the integrity of filter elements | 64 | 1992 | |
| 6,045,899 Highly assymetric, hydrophilic, microfiltration membranes having large pore diameters | 97 | 1996 | |
| 6,083,393 Hydrophilic membrane | 45 | 1997 | |
| 6,039,872 Hydrophilic membrane | 47 | 1998 | |
| 6,770,202 Porous membrane | 44 | 2002 | |
| 6,811,696 Hydrophobic membrane materials for filter venting applications | 29 | 2002 | |
| 6,884,375 Hydrophobic membrane materials for filter venting applications | 35 | 2004 | |
|
|
|||
| 4,931,186 Concentration of solids in a suspension | 52 | 1986 | |
| 4,767,539 Cleaning of hollow fiber filters utilized in lumenal gas flow | 58 | 1987 | |
| 4,876,012 Hollow fibre filter cartridge and header | 46 | 1988 | |
| 5,024,762 Concentration of solids in a suspension | 48 | 1990 | |
| 2002/0148,767 Membrane filtration manifold system | 38 | 2001 | |
| 2003/0178,365 Scouring method | 38 | 2003 | |
| 2003/0226,797 Fibre membrane arrangement | 35 | 2003 | |
|
|
|||
| 6,096,213 Puncture-resistant polyolefin membranes | 50 | 1998 | |
| 6,277,512 Polymer electrolyte membranes from mixed dispersions | 69 | 1999 | |
| 6,423,784 Acid functional fluoropolymer membranes and method of manufacture | 48 | 1999 | |
| 6,790,912 Extrudable fluoropolymer blends | 35 | 2001 | |
| 6,861,466 Fluoropolymer dispersion containing no or little low molecular weight fluorinated surfactant | 63 | 2004 | |
| 7,041,728 Aqueous dispersions of polytetrafluoroethylene having a low amount of fluorinated surfactant | 44 | 2004 | |
|
|
|||
| 4,656,865 System for analyzing permeation of a gas or vapor through a film or membrane | 61 | 1985 | |
| 4,797,187 Semi-permeable membranes prepared via reaction of cationic groups with nucleophilic groups | 49 | 1987 | |
| 4,904,426 Process for the production of fibers from poly(etheretherketone)-type polymers | 38 | 1988 | |
| 4,963,304 Process for preparing microporous membranes | 44 | 1988 | |
| 5,015,275 Isotropic microporous syndiotactic polystyrene membranes and processes for preparing the same | 36 | 1989 | |
| 5,221,478 Chromatographic separation using ion-exchange resins | 41 | 1992 | |
|
|
|||
| 4,702,836 Porous fluorine resin membrane and process for preparing the same | 41 | 1986 | |
| 6,299,773 Porous polyvinylidene fluoride resin film and process for producing the same | 40 | 1999 | |
| 6,322,703 Method for purifying aqueous suspension | 32 | 2000 | |
| 6,495,041 Method for purifying aqueous suspension | 30 | 2001 | |
|
|
|||
| 4,816,160 Cooling hollow fibre cross-flow separators | 46 | 1986 | |
| 4,793,932 Variable volume filter or concentrator | 53 | 1986 | |
| 4,935,143 Cleaning of filters | 52 | 1988 | |
| 4,921,610 Cleaning of hollow fibre filters | 76 | 1988 | |
|
|
|||
| 5,137,631 Multiple bundle permeator | 56 | 1991 | |
| 5,320,760 Method of determining filter pluggage by measuring pressures | 44 | 1992 | |
| 5,470,469 Hollow fiber cartridge | 85 | 1994 | |
|
|
|||
| 4,886,601 Column filter using bundles of long fibers | 49 | 1989 | |
| 5,209,852 Process for scrubbing porous hollow fiber membranes in hollow fiber membrane module | 79 | 1991 | |
| 5,151,191 Filtration process using hollow fiber membrane module | 61 | 1991 | |
|
|
|||
| 5,192,456 Apparatus for treating activated sludge and method of cleaning it | 96 | 1992 | |
| 5,451,317 Solid-liquid separator | 48 | 1994 | |
| 5,647,988 Method of back-washing submerged-type ceramic membrane separation apparatus | 60 | 1994 | |
|
|
|||
| 5,543,002 Method of manufacture of hollow fiber filter cartridge with porous ring | 46 | 1994 | |
| 5,554,283 Hollow fiber filter having a porous collar/ring seal | 61 | 1995 | |
| 5,531,848 Method of manufacturing of hollow fiber cartridge with porous ring | 48 | 1995 | |
|
|
|||
| 5,079,272 Porous membrane formed from interpenetrating polymer network having hydrophilic surface | 63 | 1989 | |
| 5,211,823 Process for purifying resins utilizing bipolar interface | 72 | 1991 | |
| 5,158,721 Porous membrane formed from interpenetrating polymer network having hydrophilic surface | 52 | 1991 | |
|
|
|||
| 5,094,750 Hollow fibre filter cartridge and header | 41 | 1989 | |
| 5,194,149 Filter cartridge manifold | 44 | 1991 | |
| 5,405,528 Modular microporous filter assemblies | 62 | 1992 | |
|
|
|||
| 4,302,336 Semipermeable composite membrane | 60 | 1979 | |
| 4,353,802 Semipermeable composite membrane | 48 | 1979 | |
| 4,388,189 Process for preparation of improved semipermeable composite membranes | 62 | 1980 | |
|
|
|||
| 4,744,240 Method for determining the bubble point or the largest pore of membranes or of filter materials | 56 | 1987 | |
| 5,066,401 Flat or capillary membrane based on a homogeneous mixture of polyvinylidene fluoride and a second polymer which can be rendered hydrophilic by chemical reaction | 54 | 1990 | |
|
|
|||
| 4,775,471 Hollow fiber filter device | 50 | 1986 | |
| 4,876,006 Hollow fiber filter device | 100 | 1988 | |
|
|
|||
| 6,074,718 Self supporting hollow fiber membrane and method of construction | 36 | 1996 | |
| 6,890,435 Hollow fiber microfiltration membranes and a method of making these membranes | 38 | 2002 | |
|
|
|||
| 4,708,799 Hollow fiber membrane for plasma separation | 48 | 1985 | |
| 4,968,733 Process for producing microporous powders and membranes | 72 | 1989 | |
|
|
|||
| 4,203,848 Processes of making a porous membrane material from polyvinylidene fluoride, and products | 101 | 1977 | |
| 4,632,745 Electrodeionization apparatus | 136 | 1985 | |
|
|
|||
| 5,069,065 Method for measuring wettability of porous rock | 59 | 1991 | |
| 5,297,420 Apparatus and method for measuring relative permeability and capillary pressure of porous rock | 59 | 1993 | |
|
|
|||
| 6,315,895 Dual-stage hemodiafiltration cartridge | 38 | 1999 | |
| 6,635,179 Sterile fluid filtration cartridge and method for using same | 37 | 1999 | |
|
|
|||
| 4,218,324 Filter element having removable filter media member | 56 | 1979 | |
| 4,812,235 Filter element assembly replaceable mesh pack | 48 | 1983 | |
|
|
|||
| 4,384,474 Method and apparatus for testing and using membrane filters in an on site of use housing | 59 | 1981 | |
| 4,888,115 Cross-flow filtration | 53 | 1983 | |
|
|
|||
| 4,629,563 Asymmetric membranes | 208 | 1981 | |
| 5,906,742 Microfiltration membranes having high pore density and mixed isotropic and anisotropic structure | 57 | 1997 | |
|
|
|||
| D396726 Combined air intake manifold and filter | 33 | 1997 | |
|
|
|||
| 6,994,867 Biocompatible carrier containing L-arginine | 34 | 2002 | |
|
|
|||
| 4,407,975 Polymeric membrane having maleic anhydride residues | 32 | 1982 | |
|
|
|||
| 4,385,150 Organic solution of fluorinated copolymer having carboxylic acid groups | 46 | 1981 | |
|
|
|||
| 6,264,839 Phosphonomethylated polyvinylamines and preparation and use thereof | 32 | 1993 | |
|
|
|||
| 4,248,648 Method of repairing leaks in a hollow capillary fiber diffusion device | 48 | 1979 | |
|
|
|||
| 4,968,430 Composite membranes, processes for their preparation and their use | 55 | 1989 | |
|
|
|||
| 6,723,758 Graft polymeric membranes and ion-exchange membranes formed therefrom | 30 | 2001 | |
|
|
|||
| 5,043,113 Process for formation of halogenated polymeric microporous membranes having improved strength properties | 30 | 1990 | |
|
|
|||
| 6,440,303 Fluid filter | 46 | 2001 | |
|
|
|||
| 5,389,260 Brine seal for tubular filter | 64 | 1993 | |
|
|
|||
| 6,221,247 Dioxole coated membrane module for ultrafiltration or microfiltration of aqueous suspensions | 41 | 1999 | |
|
|
|||
| 5,275,766 Method for making semi-permeable polymer membranes | 36 | 1992 | |
|
|
|||
| 4,718,270 Porosimeter and methods of assessing porosity | 54 | 1985 | |
|
|
|||
| 5,198,116 Method and apparatus for measuring the fouling potential of membrane system feeds | 45 | 1992 | |
|
|
|||
| 5,479,590 Anti-aliasing method for polynomial curves using integer arithmetics | 44 | 1994 | |
|
|
|||
| 4,779,448 Photoelectric bubble detector apparatus and method | 48 | 1986 | |
|
|
|||
| 6,337,018 Composite membrane and method for making the same | 42 | 2000 | |
|
|
|||
| 4,840,227 Process for producing a hollow fiber mass transfer module and module produced by this process | 36 | 1988 | |
|
|
|||
| 4,511,471 Filter apparatus for continuously thickening suspensions | 45 | 1983 | |
|
|
|||
| 6,721,529 Release agent donor member having fluorocarbon thermoplastic random copolymer overcoat | 51 | 2001 | |
|
|
|||
| 4,673,507 Fluid treatment process and apparatus | 50 | 1985 | |
|
|
|||
| 5,005,430 Automated membrane filter sampler | 48 | 1990 | |
|
|
|||
| 5,747,605 Mixtures of polymers including a halogen-containing polymer and compatibilized with a grafted aliphatic polyester | 30 | 1995 | |
|
|
|||
| 4,688,511 Dirt accumulation indicator for air intake filters | 65 | 1985 | |
|
|
|||
| 5,151,193 Polymer membranes on the basis of polyvinylidene fluoride, a process for the production thereof and their use | 47 | 1990 | |
|
|
|||
| 6,890,645 Photocatalytic sheet or film and its manufacturing process | 30 | 2001 | |
|
|
|||
| 6,727,305 Filler-containing polymer dispersion, method for its production and its use | 32 | 2001 | |
|
|
|||
| 4,650,596 Pour point depressants for paraffin solutions | 30 | 1985 | |
|
|
|||
| 4,193,780 Air filter construction | 56 | 1978 | |
|
|
|||
| 5,147,553 Selectively permeable barriers | 59 | 1991 | |
|
|
|||
| 4,540,490 Apparatus for filtration of a suspension | 70 | 1983 | |
|
|
|||
| 4,647,377 Filter apparatus | 71 | 1984 | |
|
|
|||
| 4,756,875 Apparatus for filtering water containing radioactive substances in nuclear power plants | 55 | 1986 | |
|
|
|||
| 4,797,211 Cross flow microfilter | 89 | 1986 | |
|
|
|||
| 4,547,289 Filtration apparatus using hollow fiber membrane | 70 | 1984 | |
|
|
|||
| 4,670,145 Multiple bundle fluid separation apparatus | 63 | 1986 | |
|
|
|||
| 5,135,663 Method of treating (meth)acrylic monomer-containing wastewater | 33 | 1991 | |
|
|
|||
| 5,066,402 Method of changing operating modes in automatic water filtering apparatus using tubular membranes | 84 | 1990 | |
|
|
|||
| 4,192,750 Stackable filter head unit | 79 | 1978 | |
|
|
|||
| 4,614,109 Method and device for testing the permeability of membrane filters | 64 | 1985 | |
|
|
|||
| 5,353,630 Apparatus for testing membrane filter integrity | 59 | 1993 | |
|
|
|||
| 5,411,663 Alcohol-insoluble nylon microporous membranes | 31 | 1993 | |
|
|
|||
| 6,280,626 Membrane separator assembly and method of cleaning the assembly utilizing gas diffuser underneath the assembly | 59 | 1999 | |
|
|
|||
| 5,480,553 Hollow fiber membrane module | 85 | 1993 | |
|
|
|||
| 4,660,411 Apparatus for measuring transmission of volatile substances through films | 51 | 1985 | |
|
|
|||
| 5,419,816 Electrolytic process and apparatus for the controlled oxidation of inorganic and organic species in aqueous solutions | 60 | 1993 | |
|
|
|||
| 5,525,220 Filtration equipment | 30 | 1994 | |
|
|
|||
| 5,484,528 Filtration equipment for hollow fiber module | 41 | 1994 | |
|
|
|||
| 4,846,970 Cross-flow filtration membrane test unit | 67 | 1987 | |
|
|
|||
| 5,607,593 Installation for making water potable with submerged filtering membranes | 104 | 1994 | |
|
|
|||
| 6,146,747 Highly porous polyvinylidene difluoride membranes | 59 | 1998 | |
|
|
|||
| 5,138,870 Apparatus for measuring water vapor permeability through sheet materials | 49 | 1991 | |
|
|
|||
| 4,810,384 Hydrophilic PVDF semipermeable membrane | 63 | 1987 | |
|
|
|||
| 5,198,162 Microporous films | 42 | 1989 | |
|
|
|||
| 5,361,625 Method and device for the measurement of barrier properties of films against gases | 53 | 1993 | |
|
|
|||
| 5,104,546 Pyrogens separations by ceramic ultrafiltration | 62 | 1990 | |
|
|
|||
| 5,477,731 Method and apparatus for detecting a fouled fluid filter | 54 | 1994 | |
|
|
|||
| 4,188,817 Method for detecting membrane leakage | 46 | 1978 | |
|
|
|||
| 6,284,135 Membrane filter apparatus with gas discharge cleaning means | 55 | 1998 | |
|
|
|||
| 5,286,324 Polytetrafluoroethylene resin porous membrane, separator making use of the porous membrane and methods of producing the porous membrane and the separator | 38 | 1992 | |
|
|
|||
| 4,451,369 Fluid separation apparatus | 93 | 1981 | |
|
|
|||
| 4,687,561 Process and apparatus for treatment of fluids, particularly demineralization of aqueous solutions | 88 | 1985 | |
|
|
|||
| 5,066,375 Introducing and removing ion-exchange and other particulates from an assembled electrodeionization stack | 92 | 1990 | |
|
|
|||
| 5,401,401 Hang on tank canister filter | 59 | 1993 | |
|
|
|||
| 4,636,296 Process and apparatus for treatment of fluids, particularly desalinization of aqueous solutions | 87 | 1985 | |
|
|
|||
| 5,531,900 Modification of polyvinylidene fluoride membrane and method of filtering | 52 | 1994 | |
|
|
|||
| 4,784,771 Method and apparatus for purifying fluids | 66 | 1987 | |
|
|
|||
| 5,076,925 Process for preparing a microporous membrane and such a membrane | 68 | 1990 | |
|
|
|||
| 4,763,612 Intake system for internal combustion engine | 48 | 1987 | |
|
|
|||
| 5,988,400 Pourous fluorocarbon membrane, method for producing thereof and cartridge filter based on said membrane | 39 | 1997 | |
|
|
|||
| 4,230,583 Supported anisotropic reverse osmosis membranes based on synthetic polyamides and processes for their preparation | 41 | 1978 | |
| 4,642,182 Multiple-disc type filter with extensible support | 61 | 1985 | |
| 4,999,038 Filter unit | 77 | 1989 | |
| H1045 Air bubble leak detection test device | 36 | 1990 | |
| 5,364,527 Apparatus and process for treating water | 40 | 1992 | |
| D396046 Steer device for an outboard motor | 32 | 1996 | |
| 6,048,454 Oil filter pack and assembly | 62 | 1997 | |
| 5,942,113 Solid-liquid separating filter medium for sewage, waste water, etc | 42 | 1997 | |
| D400890 Automotive manifold | 38 | 1997 | |
Patent Citation Ranking
Maintenance Fees
| Fee | Large entity fee | small entity fee | micro entity fee | due date |
|---|---|---|---|---|
| 7.5 Year Payment | $3600.00 | $1800.00 | $900.00 | Dec 5, 2014 |
| 11.5 Year Payment | $7400.00 | $3700.00 | $1850.00 | Dec 5, 2018 |
| Fee | Large entity fee | small entity fee | micro entity fee |
|---|---|---|---|
| Surcharge - 7.5 year - Late payment within 6 months | $160.00 | $80.00 | $40.00 |
| Surcharge - 11.5 year - Late payment within 6 months | $160.00 | $80.00 | $40.00 |
| Surcharge after expiration - Late payment is unavoidable | $700.00 | $350.00 | $175.00 |
| Surcharge after expiration - Late payment is unintentional | $1,640.00 | $820.00 | $410.00 |