Polymerization catalyst composition for ethylene oxide and proces for the production of poly(ethylene oxide) with the same
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United States of America Patent
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Nov 24, 2009
Grant Date -
Feb 16, 2006
app pub date -
Oct 30, 2003
filing date -
Nov 5, 2002
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Abstract
Provided are a polymerization catalyst composition for ethylene oxide which can give polyethylene oxide having a molecular weight lower than that of the prior art and a relatively narrow molecular weight distribution, and a process for the production of polyethylene oxide by the use of the catalyst composition. The catalyst composition makes it possible to produce polyethylene oxide having a molecular weight ranging from about 20,000 to 200,000 through direct polymerization in a high yield with economic advantage, and is characterized by comprising an organoaluminum compound and at least one member selected from among alkali metal alkoxides and alkali metal hydroxides. According to the process, polyethylene oxide having a molecular weight failing within the above range can be produced by the use of the catalyst composition under the same polymerication conditions as those of the prior art.
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