Gold complexes for catalysIS and preparation thereof
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United States of America Patent
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Aug 3, 2010
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Apr 7, 2008
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Apr 5, 2007
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Abstract
A number of cationic gold(I) and neutral gold(III) complexes have been synthesized and found to be stabilized by the use of N-heterocyclic carbene ligands. These species are often employed as in situ-generated reactive intermediates in gold catalyzed organic transformations. An isolated, well-defined cationic species was tested in gold mediated carbene transfer reactions from ethyl diazoacetate.
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