US Patent No: 8,157,908
Number of patents in Portfolio can not be more than 2000
Three dimensional printing material system and method using peroxide cure
Stats
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Apr 17, 2012
Issued date -
Jan 28, 2011
filing date -
13/016,189
serial no -
In Force
status
Importance
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Abstract
A materials system and methods are provided to enable the formation of articles by Three Dimensional Printing. The materials system includes a transition metal catalyst that facilitates the reaction of an acrylate-containing binder with a particulate material.
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First Claim
Related Publications
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International Classification(s)
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- [Patents Count]
Cited Art
| Patent Info | (Count) | # Cites | Year |
|---|---|---|---|
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| 4,575,330 Apparatus for production of three-dimensional objects by stereolithography | 476 | 1984 | |
| 4,996,010 Methods and apparatus for production of three-dimensional objects by stereolithography | 47 | 1988 | |
| 4,999,143 Methods and apparatus for production of three-dimensional objects by stereolithography | 75 | 1988 | |
| 5,015,424 Methods and apparatus for production of three-dimensional objects by stereolithography | 59 | 1988 | |
| 5,059,359 Methods and apparatus for production of three-dimensional objects by stereolithography | 54 | 1988 | |
| 5,058,988 Apparatus and method for profiling a beam | 57 | 1988 | |
| 5,059,021 Apparatus and method for correcting for drift in production of objects by stereolithography | 60 | 1988 | |
| 5,076,974 Methods of curing partially polymerized parts | 52 | 1988 | |
| 5,123,734 Apparatus and method for calibrating and normalizing a stereolithographic apparatus | 53 | 1988 | |
| 5,184,307 Method and apparatus for production of high resolution three-dimensional objects by stereolithography | 72 | 1989 | |
| 5,104,592 Method of and apparatus for production of three-dimensional objects by stereolithography with reduced curl | 62 | 1989 | |
| 4,929,402 Method for production of three-dimensional objects by stereolithography | 120 | 1989 | |
| 5,143,663 Stereolithography method and apparatus | 79 | 1989 | |
| 5,133,987 Stereolithographic apparatus and method | 60 | 1989 | |
| 5,182,056 Stereolithography method and apparatus employing various penetration depths | 77 | 1989 | |
| 5,130,064 Method of making a three dimensional object by stereolithography | 55 | 1989 | |
| 5,174,931 Method of and apparatus for making a three-dimensional product by stereolithography | 72 | 1990 | |
| 5,096,530 Resin film recoating method and apparatus | 61 | 1990 | |
| 5,141,680 Thermal stereolighography | 95 | 1990 | |
| 5,192,469 Simultaneous multiple layer curing in stereolithography | 41 | 1990 | |
| 5,209,878 Surface resolution in three-dimensional objects by inclusion of thin fill layers | 57 | 1990 | |
| 5,155,321 Radiant heating apparatus for providing uniform surface temperature useful in selective laser sintering | 70 | 1990 | |
| 5,137,662 Method and apparatus for production of three-dimensional objects by stereolithography | 54 | 1991 | |
| 5,182,055 Method of making a three-dimensional object by stereolithography | 68 | 1991 | |
| 5,248,456 Method and apparatus for cleaning stereolithographically produced objects | 67 | 1991 | |
| 5,174,943 Method for production of three-dimensional objects by stereolithography | 50 | 1991 | |
| 5,267,013 Apparatus and method for profiling a beam | 46 | 1991 | |
| 5,252,264 Apparatus and method for producing parts with multi-directional powder delivery | 107 | 1991 | |
| 5,192,559 Apparatus for building three-dimensional objects with sheets | 79 | 1991 | |
| 5,182,715 Rapid and accurate production of stereolighographic parts | 75 | 1992 | |
| 5,236,637 Method of and apparatus for production of three dimensional objects by stereolithography | 61 | 1992 | |
| 5,345,391 Method and apparatus for production of high resolution three-dimensional objects by stereolithography | 67 | 1992 | |
| 5,273,691 Stereolithographic curl reduction | 44 | 1992 | |
| 5,258,146 Method of and apparatus for measuring and controlling fluid level in stereolithography | 31 | 1992 | |
| 5,256,340 Method of making a three-dimensional object by stereolithography | 75 | 1992 | |
| 5,358,673 Applicator device and method for dispensing a liquid medium in a laser modeling machine | 44 | 1992 | |
| 5,234,636 Methods of coating stereolithographic parts | 51 | 1992 | |
| 5,238,639 Method and apparatus for stereolithographic curl balancing | 52 | 1992 | |
| 5,344,298 Apparatus for making three-dimensional objects by stereolithography | 54 | 1992 | |
| 5,342,919 Sinterable semi-crystalline powder and near-fully dense article formed therewith | 86 | 1992 | |
| 5,352,405 Thermal control of selective laser sintering via control of the laser scan | 100 | 1992 | |
| 5,430,666 Automated method and apparatus for calibration of laser scanning in a selective laser sintering apparatus | 50 | 1992 | |
| 5,610,824 Rapid and accurate production of stereolithographic parts | 28 | 1993 | |
| 5,609,812 Method of making a three-dimensional object by stereolithography | 23 | 1993 | |
| 5,501,824 Thermal stereolithography | 57 | 1993 | |
| 5,495,328 Apparatus and method for calibrating and normalizing a stereolithographic apparatus | 32 | 1993 | |
| 5,447,822 Apparatus and related method for forming a substantially flat stereolithographic working surface | 54 | 1994 | |
| 5,597,520 Simultaneous multiple layer curing in stereolithography | 38 | 1994 | |
| 5,527,877 Sinterable semi-crystalline powder and near-fully dense article formed therewith | 39 | 1994 | |
| 5,582,876 Stereographic apparatus and method | 11 | 1994 | |
| 5,693,144 Vibrationally enhanced stereolithographic recoating | 30 | 1995 | |
| 5,651,934 Recoating of stereolithographic layers | 46 | 1995 | |
| 5,688,464 Vibrationally enhanced stereolithographic recoating | 32 | 1995 | |
| 5,695,707 Thermal stereolithography | 75 | 1995 | |
| 5,676,904 Thermal stereolithography | 34 | 1995 | |
| 5,554,336 Method and apparatus for production of three-dimensional objects by stereolithography | 32 | 1995 | |
| 5,569,349 Thermal stereolithography | 36 | 1995 | |
| 5,571,471 Method of production of three-dimensional objects by stereolithography | 46 | 1995 | |
| 5,672,312 Thermal stereolithography | 35 | 1995 | |
| 5,630,981 Method for production of three-dimensional objects by stereolithography | 44 | 1995 | |
| 5,556,590 Apparatus for production of three-dimensional objects by stereolithography | 35 | 1995 | |
| 5,569,431 Method and apparatus for production of three-dimensional objects by stereolithography | 52 | 1995 | |
| 5,573,722 Method and apparatus for production of three-dimensional objects by stereolithography | 39 | 1995 | |
| 5,609,813 Method of making a three-dimensional object by stereolithography | 26 | 1995 | |
| 5,637,169 Method of building three dimensional objects with sheets | 46 | 1995 | |
| 5,667,820 Apparatus for making a solid three-dimensional article from a liquid medium | 24 | 1995 | |
| 5,711,911 Method of and apparatus for making a three-dimensional object by stereolithography | 32 | 1995 | |
| 5,772,947 Stereolithographic curl reduction | 10 | 1995 | |
| 5,870,307 Method and apparatus for production of high resolution three-dimensional objects by stereolithography | 30 | 1995 | |
| 5,733,497 Selective laser sintering with composite plastic material | 44 | 1995 | |
| 5,749,041 Method of forming three-dimensional articles using thermosetting materials | 40 | 1995 | |
| 5,665,401 Apparatus for producing an object using stereolithography | 16 | 1996 | |
| 5,648,450 Sinterable semi-crystalline powder and near-fully dense article formed therein | 41 | 1996 | |
| 5,902,441 Method of three dimensional printing | 61 | 1996 | |
| 5,943,235 Rapid prototyping system and method with support region data processing | 126 | 1996 | |
| 6,007,318 Method and apparatus for prototyping a three-dimensional object | 72 | 1996 | |
| 5,902,537 Rapid recoating of three-dimensional objects formed on a cross-sectional basis | 110 | 1997 | |
| 6,136,948 Sinterable semi-crystalline powder and near-fully dense article formed therewith | 24 | 1997 | |
| 6,416,850 Three dimensional printing materials system | 59 | 1999 | |
| 6,375,874 Method and apparatus for prototyping a three-dimensional object | 75 | 1999 | |
| 6,403,002 Method and device for producing a shaped body | 25 | 1999 | |
| 6,610,429 Three dimensional printing material system and method | 37 | 2001 | |
| 6,989,115 Method and apparatus for prototyping a three-dimensional object | 33 | 2001 | |
| 6,713,125 Infiltration of three-dimensional objects formed by solid freeform fabrication | 11 | 2002 | |
| 7,087,109 Three dimensional printing material system and method | 23 | 2002 | |
| 7,037,382 Three-dimensional printer | 13 | 2002 | |
| 7,332,537 Three dimensional printing material system and method | 9 | 2003 | |
| 2004/0166,187 Cooling techniques in solid freeform fabrication | 5 | 2004 | |
| 2005/0003,189 Thermoplastic powder material system for appearance models from 3D prinitng systems | 9 | 2004 | |
| 2005/0197,431 Compositions for three-dimensional printing of solid objects | 8 | 2005 | |
| 2006/0208,388 Material systems and methods of three-dimensional printing | 10 | 2006 | |
| 2008/0138,515 Three Dimensional Printing Material System and Method Using Peroxide Cure | 4 | 2007 | |
| 2008/0187,711 Three-Dimensional Printing Material System With Improved Color, Article Performance, and Ease of Use | 4 | 2008 | |
| 2008/0281,019 THREE DIMENSIONAL PRINTING MATERIAL SYSTEM AND METHOD USING PLASTICIZER-ASSISTED SINTERING | 4 | 2008 | |
| 2011/0156,301 THREE DIMENSIONAL PRINTING MATERIAL SYSTEM AND METHOD USING PLASTICIZER-ASSISTED SINTERING | 1 | 2011 | |
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| 4,863,538 Method and apparatus for producing parts by selective sintering | 295 | 1986 | |
| 4,938,816 Selective laser sintering with assisted powder handling | 123 | 1989 | |
| 4,944,817 Multiple material systems for selective beam sintering | 155 | 1989 | |
| 5,017,317 Gas phase selective beam deposition | 43 | 1989 | |
| 5,132,143 Method for producing parts | 106 | 1990 | |
| 5,017,753 Method and apparatus for producing parts by selective sintering | 121 | 1990 | |
| 5,053,090 Selective laser sintering with assisted powder handling | 82 | 1990 | |
| 5,076,869 Multiple material systems for selective beam sintering | 108 | 1990 | |
| 5,147,587 Method of producing parts and molds using composite ceramic powders | 71 | 1991 | |
| 5,135,695 Positioning, focusing and monitoring of gas phase selective beam deposition | 29 | 1991 | |
| 5,169,579 Catalyst and plasma assisted nucleation and renucleation of gas phase selective laser deposition | 39 | 1991 | |
| 5,316,580 Method and apparatus for producing parts by selective sintering | 77 | 1992 | |
| 5,296,062 Multiple material systems for selective beam sintering | 54 | 1992 | |
| 5,306,447 Method and apparatus for direct use of low pressure vapor from liquid or solid precursors for selected area laser deposition | 31 | 1992 | |
| 5,382,308 Multiple material systems for selective beam sintering | 55 | 1994 | |
| 5,597,589 Apparatus for producing parts by selective sintering | 45 | 1994 | |
| 5,611,883 Joining ceramics and attaching fasteners to ceramics by gas phase selective beam deposition | 23 | 1995 | |
| 5,616,294 Method for producing parts by infiltration of porous intermediate parts | 51 | 1995 | |
| 5,639,070 Method for producing parts by selective sintering | 53 | 1995 | |
| 5,640,667 Laser-directed fabrication of full-density metal articles using hot isostatic processing | 41 | 1995 | |
| 6,540,784 Artificial bone implants | 27 | 2001 | |
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| 5,468,886 (Cyclo)aliphatic epoxy compounds | 14 | 1993 | |
| 5,437,964 Stereolithography using vinyl ether-epoxide polymers | 34 | 1994 | |
| 5,470,689 Polymerisable compositions containing tetraacrylates | 16 | 1994 | |
| 5,506,087 Stereolithography using vinyl ether based polymers | 16 | 1994 | |
| 5,510,226 Stereolithography using vinyl ether-epoxide polymers | 27 | 1994 | |
| 5,494,618 Increasing the useful range of cationic photoinitiators in stereolithography | 24 | 1994 | |
| 5,495,029 (Meth)acrylates containing urethane groups | 27 | 1994 | |
| 5,461,088 Liquid radiation-curable formulation, in particular for use in stereolithography | 16 | 1994 | |
| 5,605,941 Vinyl ether compounds having additional functional groups other than vinyl ether groups and the use thereof in the formulation of curable compositions | 25 | 1994 | |
| 5,573,889 Process for adjusting the sensitivity to radiation of photopolymerizable compositions | 34 | 1995 | |
| 5,705,116 Increasing the useful range of cationic photoinitiators in stereolithography | 14 | 1995 | |
| 5,599,651 (Cyclo)aliphatic epoxy compounds | 16 | 1995 | |
| 5,658,712 (Meth)acrylates containing urethane groups | 10 | 1995 | |
| 5,705,316 Vinyl ether compounds having additional functional groups other than vinyl ether groups and the use thereof in the formulation of curable compositions | 20 | 1995 | |
| 5,645,973 Process for adjusting the sensitivity to radiation of photopolymerizable compositions | 14 | 1996 | |
| 5,783,358 Stabilization of liquid radiation-curable compositions against undesired premature polymerization | 21 | 1996 | |
| 5,677,107 Production of three-dimensional objects | 57 | 1996 | |
| 2004/0038,009 Water-based material systems and methods for 3D printing | 11 | 2002 | |
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| 5,204,055 Three-dimensional printing techniques | 328 | 1989 | |
| 5,512,162 Method for photo-forming small shaped metal containing articles from porous precursors | 96 | 1992 | |
| 5,490,882 Process for removing loose powder particles from interior passages of a body | 56 | 1992 | |
| 5,514,378 Biocompatible polymer membranes and methods of preparation of three dimensional membrane structures | 142 | 1993 | |
| 5,340,656 Three-dimensional printing techniques | 146 | 1993 | |
| 5,450,205 Apparatus and method for real-time measurement of thin film layer thickness and changes thereof | 164 | 1993 | |
| 5,684,713 Method and apparatus for the recursive design of physical structures | 64 | 1993 | |
| 5,490,962 Preparation of medical devices by solid free-form fabrication methods | 188 | 1993 | |
| 5,518,680 Tissue regeneration matrices by solid free form fabrication techniques | 162 | 1994 | |
| 5,660,621 Binder composition for use in three dimensional printing | 31 | 1995 | |
| 5,940,674 Three-dimensional product manufacture using masks | 19 | 1997 | |
| 5,851,465 Binder composition for use in three dimensional printing | 35 | 1997 | |
| 6,397,922 Molds for casting with customized internal structure to collapse upon cooling and to facilitate control of heat transfer | 14 | 2000 | |
| 2003/0143,268 System and method for uniaxial compression of an article, such as a three-dimensionally printed dosage form | 18 | 2002 | |
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| 4,942,060 Solid imaging method utilizing photohardenable compositions of self limiting thickness by phase separation | 51 | 1989 | |
| 5,051,334 Solid imaging method using photohardenable compositions containing hollow spheres | 11 | 1989 | |
| 5,143,817 Solid imaging system | 42 | 1989 | |
| 5,094,935 Method and apparatus for fabricating three dimensional objects from photoformed precursor sheets | 42 | 1990 | |
| 5,158,858 Solid imaging system using differential tension elastomeric film | 24 | 1990 | |
| 5,122,441 Method for fabricating an integral three-dimensional object from layers of a photoformable composition | 30 | 1990 | |
| 5,176,188 Investment casting method and pattern material comprising thermally-collapsible expanded microspheres | 35 | 1991 | |
| 5,474,719 Method for forming solid objects utilizing viscosity reducible compositions | 58 | 1991 | |
| 5,391,072 Solid imaging apparatus having a semi-permeable film | 37 | 1992 | |
| 5,364,889 Investment casting pattern material comprising thermally-collapsible expanded microspheres | 17 | 1992 | |
| 5,429,908 Exposure method for reducing distortion in models produced through solid imaging by forming a non-continuous image of a pattern which is then imaged to form a continuous hardened image of the pattern | 31 | 1993 | |
| 5,707,780 Photohardenable epoxy composition | 31 | 1996 | |
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| 5,121,329 Apparatus and method for creating three-dimensional objects | 259 | 1989 | |
| 5,340,433 Modeling apparatus for three-dimensional objects | 176 | 1992 | |
| 5,303,141 Model generation system having closed-loop extrusion nozzle positioning | 125 | 1993 | |
| 5,426,722 Method for optimizing the motion of a multi-axis robot | 37 | 1993 | |
| 5,402,351 Model generation system having closed-loop extrusion nozzle positioning | 85 | 1994 | |
| 5,491,643 Method for optimizing parameters characteristic of an object developed in a rapid prototyping system | 26 | 1994 | |
| 5,503,785 Process of support removal for fused deposition modeling | 110 | 1994 | |
| 5,587,913 Method employing sequential two-dimensional geometry for producing shells for fabrication by a rapid prototyping system | 55 | 1994 | |
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| 5,534,104 Method and apparatus for production of three-dimensional objects | 15 | 1994 | |
| 5,658,412 Method and apparatus for producing a three-dimensional object | 56 | 1994 | |
| 5,536,467 Method and apparatus for producing a three-dimensional object | 17 | 1994 | |
| 5,460,758 Method and apparatus for production of a three-dimensional object | 58 | 1995 | |
| 5,753,274 Apparatus for producing a three-dimensional object | 42 | 1996 | |
| 5,730,925 Method and apparatus for producing a three-dimensional object | 40 | 1996 | |
| 5,753,171 Method and apparatus for producing a three-dimensional object | 26 | 1996 | |
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| 4,961,154 Three dimensional modelling apparatus | 162 | 1987 | |
| 5,031,120 Three dimensional modelling apparatus | 86 | 1988 | |
| 5,287,435 Three dimensional modeling | 76 | 1990 | |
| 5,263,130 Three dimensional modelling apparatus | 68 | 1991 | |
| 5,386,500 Three dimensional modeling apparatus | 35 | 1992 | |
| 5,519,816 Three dimensional modeling apparatus | 18 | 1994 | |
| 2005/0104,241 Apparatus and method for three dimensional model printing | 11 | 2004 | |
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| 4,665,492 Computer automated manufacturing process and system | 181 | 1984 | |
| 5,216,616 System and method for computer automated manufacture with reduced object shape distortion | 106 | 1989 | |
| 5,555,176 Apparatus and method for making three-dimensional articles using bursts of droplets | 51 | 1994 | |
| 5,572,431 Apparatus and method for thermal normalization in three-dimensional article manufacturing | 22 | 1994 | |
| 5,633,021 Apparatus for making a three-dimensional article | 32 | 1994 | |
| 5,717,599 Apparatus and method for dispensing build material to make a three-dimensional article | 40 | 1994 | |
| 5,700,406 Process of and apparatus for making a three-dimensional article | 20 | 1996 | |
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| 5,128,235 Method of forming a three-dimensional object comprising additives imparting reduction of shrinkage to photohardenable compositions | 19 | 1989 | |
| 4,996,282 Cationically curable polyurethane compositions having vinyl ether functionality | 15 | 1989 | |
| 4,942,001 Method of forming a three-dimensional object by stereolithography and composition therefore | 49 | 1989 | |
| 5,175,077 Solid imaging system using photohardening inhibition | 23 | 1990 | |
| 5,236,812 Solid imaging method and apparatus | 37 | 1991 | |
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| 7,049,363 Material system for use in three dimensional printing | 5 | 2001 | |
| 7,285,234 Process and device for producing solid bodies by sequential layer buildup | 7 | 2004 | |
| 2004/0173,946 Process for quality control for a powder based layer building up process | 8 | 2004 | |
| 2005/0212,163 Component build up in layers and process for production thereof | 8 | 2005 | |
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| 5,275,916 Direct-image type lithographic printing plate precursor | 13 | 1992 | |
| 7,300,613 Process for producing three-dimensional model, and three-dimensional model | 8 | 2004 | |
| 7,674,423 Process for producing three-dimensional model | 2 | 2004 | |
| 2007/0007,698 Method of producting three-dimensional model | 7 | 2004 | |
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| 5,173,220 Method of manufacturing a three-dimensional plastic article | 135 | 1991 | |
| 5,264,061 Method of forming a three-dimensional printed circuit assembly | 146 | 1992 | |
| 5,439,622 Method and apparatus for producing molded parts | 48 | 1993 | |
| 5,659,478 Rapid product realization process | 44 | 1995 | |
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| 5,198,159 Process of fabricating three-dimensional objects from a light curable resin liquid | 44 | 1990 | |
| 5,139,711 Process of and apparatus for making three dimensional objects | 20 | 1990 | |
| 5,238,614 Process of fabricating three-dimensional objects from a light curable resin liquid | 32 | 1992 | |
| 5,503,793 Process of fabricating a three-dimensional object from a light curable liquid resin | 10 | 1994 | |
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| 5,247,180 Stereolithographic apparatus and method of use | 96 | 1991 | |
| 5,260,009 System, method, and process for making three-dimensional objects | 97 | 1992 | |
| 5,593,531 System, method and process for fabrication of 3-dimensional objects by a static electrostatic imaging and lamination device | 17 | 1994 | |
| 5,594,652 Method and apparatus for the computer-controlled manufacture of three-dimensional objects from computer data | 111 | 1995 | |
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| 2001/0050,031 Compositions for three-dimensional printing of solid objects | 45 | 2001 | |
| 2005/0059,757 Absorbent fillers for three-dimensional printing | 9 | 2004 | |
| 2006/0230,984 Three dimensional printing material system and method | 10 | 2006 | |
| 2007/0241,482 Production of three-dimensional objects by use of electromagnetic radiation | 8 | 2007 | |
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| 4,752,352 Apparatus and method for forming an integral object from laminations | 169 | 1987 | |
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| 5,730,817 Laminated object manufacturing system | 35 | 1996 | |
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| 5,506,046 Articles of manufacture fashioned from sheets having a highly inorganically filled organic polymer matrix | 75 | 1993 | |
| 5,800,756 Methods for manufacturing containers and other articles from hydraulically settable mixtures | 22 | 1995 | |
| 5,738,921 Compositions and methods for manufacturing sealable, liquid-tight containers comprising an inorganically filled matrix | 38 | 1996 | |
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| 6,742,456 Rapid prototyping material systems | 14 | 2002 | |
| 6,930,144 Cement system including a binder for use in freeform fabrication | 7 | 2003 | |
| 7,120,512 Method and a system for solid freeform fabricating using non-reactive powder | 8 | 2003 | |
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| 5,009,585 Optical molding apparatus and movable base device therefor | 18 | 1989 | |
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| 5,151,813 Method and apparatus for producing three-dimensional objects | 25 | 1990 | |
| 5,248,249 Three-dimensional structure forming apparatus provided with a liquid-level control system for a main resin tank | 23 | 1992 | |
| 5,525,051 Optical molding apparatus | 13 | 1995 | |
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| 4,844,144 Investment casting utilizing patterns produced by stereolithography | 86 | 1988 | |
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| 4,945,032 Stereolithography using repeated exposures to increase strength and reduce distortion | 46 | 1989 | |
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| 2002/0106,412 Method and materials for controlling migration of binder liquid in a powder | 20 | 2001 | |
| 2003/0173,695 Rapid prototyping and manufacturing process | 31 | 2003 | |
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| 6,348,679 RF active compositions for use in adhesion, bonding and coating | 81 | 2000 | |
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| 5,059,266 Apparatus and method for forming three-dimensional article | 163 | 1990 | |
| 5,149,548 Apparatus for forming three-dimension article | 62 | 1990 | |
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| 5,157,423 Apparatus for pattern generation on a dielectric substrate | 31 | 1991 | |
| 5,289,214 Apparatus for information transfer including a dielectric element and generally non-imagewise charge service | 27 | 1991 | |
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| 5,622,577 Rapid prototyping process and cooling chamber therefor | 29 | 1995 | |
| 5,705,117 Method of combining metal and ceramic inserts into stereolithography components | 133 | 1996 | |
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| 6,243,616 Method and device for producing three-dimensional objects | 11 | 1998 | |
| 2004/0232,583 Process for producing three-dimensional objects by means of microwave radiation | 41 | 2004 | |
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| 2007/0029,698 Layered manufactured articles having small-diameter fluid conduction vents and method of making same | 8 | 2004 | |
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| 5,182,134 Radio frequency cure of thermoset-receptor compositions | 30 | 1992 | |
| 5,328,539 Radio frequency heating of thermoplastic receptor compositions | 37 | 1992 | |
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| 5,296,335 Method for manufacturing fiber-reinforced parts utilizing stereolithography tooling | 21 | 1993 | |
| 5,603,797 Flexible reinforced rubber part manufacturing process utilizing stereolithography tooling | 16 | 1995 | |
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| 5,500,069 Three dimensional object-forming method | 15 | 1994 | |
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| 5,506,607 3-D model maker | 64 | 1995 | |
| 5,740,051 3-D model making | 75 | 1995 | |
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| 6,378,974 Ink jet method with improved tonal range | 8 | 1999 | |
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| 6,077,887 Polyelectrolyte composition | 21 | 1998 | |
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| 5,355,318 Method of manufacturing a fractal object by using steriolithography and a fractal object obtained by performing such a method | 60 | 1993 | |
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| 5,433,280 Fabrication method for rotary bits and bit components and bits and components produced thereby | 96 | 1994 | |
|
|
|||
| 5,697,043 Method of freeform fabrication by selective gelation of powder suspensions | 27 | 1996 | |
|
|
|||
| 5,376,320 Process of producing rottable thin-walled shaped bodies made of starch | 47 | 1992 | |
|
|
|||
| 5,370,692 Rapid, customized bone prosthesis | 104 | 1992 | |
|
|
|||
| 5,204,823 Method and apparatus for high-speed layer thickness curing in 3-D model making | 16 | 1991 | |
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|
|||
| 5,965,776 Alkoxyphenyl-substituted bisacylphosphine oxides | 17 | 1995 | |
|
|
|||
| 5,596,504 Apparatus and method for layered modeling of intended objects represented in STL format and adaptive slicing thereof | 30 | 1995 | |
|
|
|||
| 5,139,338 Method and apparatus for volumetric digitization of 3-dimensional objects | 36 | 1989 | |
|
|
|||
| 6,884,311 Method of image transfer on a colored base | 14 | 2000 | |
|
|
|||
| 5,183,598 Process of and apparatus for making three-dimensional objects | 34 | 1991 | |
|
|
|||
| 5,626,919 Solid imaging apparatus and method with coating station | 31 | 1992 | |
|
|
|||
| 4,247,508 Molding process | 158 | 1979 | |
|
|
|||
| 5,703,138 Oxygen-curable coating composition | 10 | 1996 | |
|
|
|||
| 4,443,392 Process for the production of molded decorative articles from a hardenable substance based on thermosetting synthetic resin | 17 | 1981 | |
|
|
|||
| 4,758,278 Magnesium oxide powder for workable, rapid-setting phosphate-containing cement compositions | 14 | 1986 | |
|
|
|||
| 5,660,900 Inorganically filled, starch-bound compositions for manufacturing containers and other articles having a thermodynamically controlled cellular matrix | 43 | 1994 | |
|
|
|||
| 4,940,412 Method of manufacturing anatomical models | 23 | 1988 | |
|
|
|||
| 5,348,693 Formation of three dimensional objects and assemblies | 24 | 1991 | |
|
|
|||
| 4,369,025 Apparatus for manufacturing elements by means of a hardenable binding agent to which a liquid is added | 33 | 1980 | |
|
|
|||
| 5,674,921 Radiation-curable, urethane-acrylate prepolymers and crosslinked polymers | 20 | 1995 | |
|
|
|||
| 5,385,772 Pressure-sensitive adhesive systems with filler | 22 | 1991 | |
|
|
|||
| 4,288,861 Three-dimensional systems | 84 | 1979 | |
|
|
|||
| 5,746,967 Method of curing thermoset resin with visible light | 12 | 1996 | |
|
|
|||
| 5,649,277 Process and apparatus for the free-forming manufacture of three dimensional components of predetermined shape | 21 | 1994 | |
|
|
|||
| 5,727,138 Method of and apparatus for generating three-dimensional model | 13 | 1995 | |
|
|
|||
| 5,632,848 Continuous processing equipment for making fiberboard | 35 | 1995 | |
|
|
|||
| 5,616,293 Rapid making of a prototype part or mold using stereolithography model | 26 | 1995 | |
|
|
|||
| 6,299,677 Binders for cores and molds | 10 | 1999 | |
|
|
|||
| 5,707,578 Method for making mold inserts | 15 | 1996 | |
|
|
|||
| 5,573,721 Use of a support liquid to manufacture three-dimensional objects | 29 | 1995 | |
|
|
|||
| 5,096,491 Aqueous starch slurry adhesive | 10 | 1990 | |
|
|
|||
| 2005/0179,167 Infiltrant system for rapid prototyping process | 7 | 2004 | |
|
|
|||
| 5,713,410 Bone prostheses with direct cast macrotextured surface regions and method for manufacturing the same | 23 | 1995 | |
|
|
|||
| 5,164,882 Ceramic capacitor | 24 | 1991 | |
|
|
|||
| 5,429,788 Apparatus and method for depositing particulate material in a composite substrate | 49 | 1994 | |
|
|
|||
| 5,015,312 Method and apparatus for constructing a three-dimensional surface of predetermined shape and color | 74 | 1988 | |
|
|
|||
| 2007/0135,531 White solid photoinitiator in the form of powder and preparation thereof | 5 | 2004 | |
|
|
|||
| 5,598,340 Method of producing industrial components by the action of light on a polymerizable or crosslinkable liquid substance without requiring supports | 19 | 1995 | |
|
|
|||
| 4,310,996 Cement reinforced gypsum foam with mineral wool | 67 | 1980 | |
|
|
|||
| 5,167,882 Stereolithography method | 29 | 1991 | |
|
|
|||
| 5,342,566 Method of manufacturing fiber gypsum board | 53 | 1990 | |
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|
|||
| 6,363,606 Process for forming integrated structures using three dimensional printing techniques | 15 | 1998 | |
|
|
|||
| 5,134,569 System and method for computer automated manufacturing using fluent material | 107 | 1989 | |
|
|
|||
| 5,595,703 Method for supporting an object made by means of stereolithography or another rapid prototype production method | 47 | 1995 | |
|
|
|||
| 4,943,928 Elongated carrier with a plurality of spot-sources of heat for use with stereolithographic system | 23 | 1988 | |
|
|
|||
| 5,387,380 Three-dimensional printing techniques | 183 | 1992 | |
|
|
|||
| 5,393,613 Composition for three-dimensional metal fabrication using a laser | 35 | 1993 | |
|
|
|||
| 5,507,336 Method of constructing fully dense metal molds and parts | 21 | 1995 | |
|
|
|||
| 6,799,959 Apparatus for forming a three-dimensional product | 13 | 2000 | |
|
|
|||
| 2005/0001,356 Apparatus for forming a three-dimensional product | 7 | 2004 | |
|
|
|||
| 5,071,503 Method and apparatus for making three-dimensional objects | 35 | 1989 | |
|
|
|||
| 5,641,448 Method of producing plastic injection molds for prototype parts | 51 | 1996 | |
|
|
|||
| 6,740,423 Colored building boards, manufacturing methods thereof | 13 | 2001 | |
|
|
|||
| 5,107,395 Method of producing insulating oil comprising dibenzylbenzene | 5 | 1991 | |
|
|
|||
| 5,415,820 Method of making photo-solidified object having unsolidified liquid ejecting ports | 18 | 1993 | |
|
|
|||
| 5,391,460 Resin composition and process for investment casting using stereolithography | 17 | 1993 | |
|
|
|||
| 2005/0110,177 Mass production of shells and models for dental restorations produced by solid free-form fabrication methods | 11 | 2004 | |
|
|
|||
| 6,136,088 Rapid setting, high early strength binders | 32 | 1997 | |
|
|
|||
| 5,071,337 Apparatus for forming a solid three-dimensional article from a liquid medium | 40 | 1990 | |
|
|
|||
| 5,555,481 Method of producing solid parts using two distinct classes of materials | 33 | 1995 | |
|
|
|||
| 5,273,581 Method of making a hydraulic binder settable upon combination with water | 4 | 1989 | |
|
|
|||
| 5,698,485 Process for producing ceramic microstructures from polymeric precursors | 22 | 1996 | |
|
|
|||
| 6,071,675 On-press development of a lithographic plate comprising dispersed solid particles | 46 | 1999 | |
|
|
|||
| 5,345,414 Semiconductor memory device having ferroelectric film | 52 | 1993 | |
|
|
|||
| 5,738,817 Solid freeform fabrication methods | 113 | 1996 | |
|
|
|||
| 6,433,038 Photocurable ink composition for ink jet recording and ink jet recording method using the same | 14 | 2000 | |
|
|
|||
| 5,155,324 Method for selective laser sintering with layerwise cross-scanning | 106 | 1990 | |
|
|
|||
| 5,545,367 Rapid prototype three dimensional stereolithography | 181 | 1993 | |
|
|
|||
| 6,531,086 Method and device for manufacturing three-dimensional bodies | 16 | 1999 | |
|
|
|||
| 4,755,227 Production of solid phosphorus pentioxide containing materials for fast-setting cements | 16 | 1985 | |
|
|
|||
| 5,653,925 Method for controlled porosity three-dimensional modeling | 55 | 1995 | |
|
|
|||
| 5,650,260 Method and apparatus for fabricating three-dimensional object | 24 | 1994 | |
|
|
|||
| 5,948,874 Acid catalyzed polymerization | 8 | 1998 | |
|
|
|||
| 4,303,556 Spray-dried detergent compositions | 20 | 1979 | |
|
|
|||
| 5,639,402 Method for fabricating artificial bone implant green parts | 68 | 1994 | |
|
|
|||
| 6,112,109 Constructive modelling of articles | 69 | 1998 | |
|
|
|||
| 5,718,279 Method for laminate forming a sand mould and a method for producing a casting using the same | 17 | 1996 | |
|
|
|||
| 5,498,782 Distortion control additives for ultraviolet-curable compositions | 9 | 1993 | |
|
|
|||
| 5,534,059 Machinable plaster | 41 | 1995 | |
|
|
|||
| 5,482,659 Method of post processing stereolithographically produced objects | 42 | 1994 | |
|
|
|||
| 5,656,230 Additive fabrication method | 35 | 1996 | |
|
|
|||
| 5,663,883 Rapid prototyping method | 30 | 1995 | |
|
|
|||
| 4,613,627 Process for the manufacture of shaped fibrous products and the resultant product | 145 | 1983 | |
|
|
|||
| 2005/0017,394 Methods and systems for the manufacture of layered three-dimensional forms | 32 | 2004 | |
|
|
|||
| 5,418,112 Photosensitive compositions useful in three-dimensional part-building and having improved photospeed | 38 | 1993 | |
|
|
|||
| 6,193,922 Method for making a three-dimensional body | 38 | 1999 | |
|
|
|||
| 5,432,045 Photo-solidification modeling apparatus and photo-solidification modeling method having an improved recoating process | 14 | 1994 | |
|
|
|||
| 4,752,498 Method and apparatus for production of three-dimensional objects by photosolidification | 138 | 1987 | |
| 4,801,477 Method and apparatus for production of three-dimensional objects by photosolidification | 82 | 1987 | |
| 5,135,379 Apparatus for production of three-dimensional objects by photosolidification | 18 | 1988 | |
| 5,088,047 Automated manufacturing system using thin sections | 66 | 1989 | |
| 5,025,898 Drum brake | 4 | 1990 | |
| 5,171,490 Method and apparatus for production of three-dimensional objects by irradiation of photopolymers | 67 | 1990 | |
| 5,127,037 Apparatus for forming a three-dimensional reproduction of an object from laminations | 72 | 1990 | |
| 5,278,442 Electronic packages and smart structures formed by thermal spray deposition | 144 | 1991 | |
| 5,207,371 Method and apparatus for fabrication of three-dimensional metal articles by weld deposition | 58 | 1991 | |
| 5,203,944 Method for fabrication of three-dimensional articles by thermal spray deposition using masks as support structures | 31 | 1991 | |
| 5,204,124 Continuous extruded bead object fabrication apparatus | 24 | 1991 | |
| 5,217,653 Method and apparatus for producing a stepless 3-dimensional object by stereolithography | 25 | 1992 | |
| 5,352,310 Actinic activation shaping system and method | 24 | 1992 | |
| 5,306,446 Apparatus with roller and for irradiation of photopolymers | 32 | 1992 | |
| 5,281,789 Method and apparatus for depositing molten metal | 31 | 1992 | |
| 5,286,573 Method and support structures for creation of objects by layer deposition | 49 | 1992 | |
| 5,301,415 Method for fabrication of three-dimensional articles | 66 | 1993 | |
| 5,435,902 Method of incremental object fabrication | 27 | 1993 | |
| 5,514,232 Method and apparatus for automatic fabrication of three-dimensional objects | 57 | 1993 | |
| 5,639,413 Methods and compositions related to stereolithography | 25 | 1995 | |
| 5,614,075 Method of incremental object fabrication | 46 | 1995 | |
| 5,976,339 Method of incremental layered object fabrication | 28 | 1997 | |
Patent Citation Ranking
Maintenance Fees
| Fee | Large entity fee | small entity fee | micro entity fee | due date |
|---|---|---|---|---|
| 3.5 Year Payment | $1600.00 | $800.00 | $400.00 | Oct 17, 2015 |
| 7.5 Year Payment | $3600.00 | $1800.00 | $900.00 | Oct 17, 2019 |
| 11.5 Year Payment | $7400.00 | $3700.00 | $1850.00 | Oct 17, 2023 |
| Fee | Large entity fee | small entity fee | micro entity fee |
|---|---|---|---|
| Surcharge - 3.5 year - Late payment within 6 months | $160.00 | $80.00 | $40.00 |
| Surcharge - 7.5 year - Late payment within 6 months | $160.00 | $80.00 | $40.00 |
| Surcharge - 11.5 year - Late payment within 6 months | $160.00 | $80.00 | $40.00 |
| Surcharge after expiration - Late payment is unavoidable | $700.00 | $350.00 | $175.00 |
| Surcharge after expiration - Late payment is unintentional | $1,640.00 | $820.00 | $410.00 |