Process for preparing fluorine-containing propene by gas-phase fluorination

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United States of America Patent

PATENT NO 8420872
APP PUB NO 20110124929A1
SERIAL NO

13054831

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Abstract

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The present invention provides a process for preparing a fluorine-containing propene represented by the chemical formula CF3CF═CX1X2, wherein X1 is a hydrogen atom or chlorine atom, and X2 is a fluorine atom, chlorine atom, or hydrogen atom, by reacting a halogenated propene represented by the chemical formula CCIYZCF═CX1X2, wherein X1 and X2 are the same as above, and Y and Z may be the same or different and individually indicate a fluorine atom or chlorine atom, with anhydrous hydrogen fluoride in a gas phase in the presence of a chromium oxide or a fluorinated chromium oxide as a fluorination catalyst. The process of the present invention provides a fluorine-containing propene represented by the chemical formula CF3CF═CClX, wherein X is Cl, H or F, under relatively mild conditions at a high yield.

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Patent Owner(s)

Patent OwnerAddress
DAIKIN INDUSTRIES LTDOSAKA

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Nose, Masatoshi Settsu, JP 27 187
Sugiyama, Akinari Settsu, JP 38 151
Suzuki, Atsushi Settsu, JP 559 5650

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