Electrochemical process for the recovery of metallic iron and chlorine values from iron-rich metal chloride wastes

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United States of America Patent

PATENT NO 8784639
APP PUB NO 20110114500A1
SERIAL NO

12933653

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Abstract

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An electrochemical process for the concurrent recovery of iron metal and chlorine gas from an iron-rich metal chloride solution, comprising electrolysing the iron-rich metal chloride solution in an electrolyser comprising a cathodic compartment equipped with a cathode having a hydrogen overpotential higher than that of iron and containing a catholyte having a pH below about 2, an anodic compartment equipped with an anode and containing an anolyte, and a separator allowing for anion passage, the electrolysing step comprising circulating the iron-rich metal chloride solution in a non-anodic compartment of the electrolyser, thereby causing iron to be electrodeposited at the cathode and chlorine gas to evolve at the anode, and leaving an iron-depleted solution, which is recirculated, at least in part, to the iron-rich metal chloride solution. The iron-rich metal chloride solution may originate from carbo-chlorination wastes, spent acid leaching liquors or pickling liquors.

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Patent Owner(s)

Patent OwnerAddress
RIO TINTO FER ET TITANE INCSOREL-TRACY QC J3R 1M6

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Cardarelli, François Montreal, CA 3 43
Hudon, Guillaume Sorel-Tracy, CA 1 3
Lefebvre, Sylvain Sorel-Tracy, CA 29 199
Tousignant, Claude Sorel-Tracy, CA 1 3

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