High productivity Kolbe reaction process for transformation of fatty acids derived from plant oil and animal fat
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United States of America Patent
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Feb 24, 2015
Grant Date -
Oct 30, 2014
app pub date -
Jul 15, 2014
filing date -
Feb 1, 2011
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Abstract
Oils from plants and animal fats are hydrolyzed to fatty acids for a Kolbe reaction. The invention relates to a high productivity Kolbe reaction process for electrochemically decarboxylating C4-C28 fatty acids using small amounts of acetic acid to lower anodic passivation voltage and synthesizing C6-C54 hydrocarbons. The C6-C54 undergo olefin metathesis and/or hydroisomerization reaction process to synthesize heavy fuel oil, diesel fuel, kerosene fuel, lubricant base oil, and linear alpha olefin products useful as precursors for polymers, detergents, and other fine chemicals.
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