Photocatalyst with enhanced stability for hydrogen production and oxidative reactions

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United States of America Patent

PATENT NO 9044746
APP PUB NO 20130180861A1
SERIAL NO

13824583

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A Ti02-based photocatalyst is fabricated as a composite of titania with adhered nanostructures which contain a non-noble metal in galvanic contact with a noble metal. The catalyst effectively overcome aging and/or deactivation effects observed in a system free of the non-noble metal. The composite material showed a corrosion protective effect on the photoactivity of fresh catalyst for over 180-240 days, and it enhanced the rate of the water reduction reaction relative to bare Ti02. Variations in porosity and non-noble metal content of the alloy portion of the nanostructures influenced the performance of the catalyst composite. The protective effect of the non-noble metal is through a cathodic corrosion protection mechanism.

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Patent Owner(s)

Patent OwnerAddress
NORTHEASTERN UNIVERSITYC/O THE CENTER FOR RESEARCH INNOVATION 360 HUNTINGTON AVENUE BOSTON MA 02115

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Lucatero, Savidra Boston, US 1 2
Podlaha-Murphy, Elizabeth J West Roxbury, US 3 17

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