Nickel and cobalt recovery using continuous ion exchange

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United States of America Patent

PATENT NO 9068247
APP PUB NO 20150096412A1
SERIAL NO

14241746

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ATTORNEY / AGENT: (SPONSORED)

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Abstract

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A method for recovering nickel and cobalt from a PLS:

    (a) passing the PLS through an ion exchange bed to load nickel onto the ion exchange resin and produce a cobalt-containing raffinate solution,(b) passing sulfuric acid through the loaded bed to strip nickel from the resin and produce a nickel-containing eluate,(c) rinsing the stripped ion exchange bed,(d) adjusting the pH of the cobalt-containing raffinate solution to a pH of at least 2.3,(e) passing the cobalt-containing raffinate solution through an ion exchange bed to pre-load cobalt on the ion exchange resin,(f) repeating step (a) though (e) until the cobalt concentration of the cobalt-containing raffinate solution increases to >2× of the PLS,(g) removing a portion of the cobalt-containing raffinate solution of step (d) from the nickel recovery circuit, and(h) passing a portion of the cobalt-containing raffinate solution from step (d) to step (e).

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Patent Owner(s)

Patent OwnerAddress
DOW GLOBAL TECHNOLOGIES LLC2211 H H DOW WAY MIDLAND MI 48674

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Eicher, Christopher R Midland, US 6 12
Marston, Charles R Midland, US 21 175

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