Process for the production of a mixture comprising cyclohexanone and cyclohexanol from phenol

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United States of America Patent

PATENT NO 9388107
APP PUB NO 20150158802A1
SERIAL NO

14408614

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Abstract

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The present invention provides a process for continuously preparing a mixture of cyclohexanone and cyclohexanol comprising, a) hydrogenating phenol with gaseous hydrogen, in the presence of platinum or palladium, in a hydrogenation reactor, to produce a hydrogenation product stream comprising cyclohexanone, cyclohexanol, phenol and hydrogen; b) cooling the hydrogenation product stream to a temperature such that the fraction of phenol by mass in a first gas phase is lower than the fraction of phenol by mass in a first liquid phase; c) separating the first gas phase from the first liquid phase; d) returning at least part of the first gas phase to the hydrogenation reactor; e) heating the first liquid phase; f) purifying the first liquid phase by distillation; characterized in that heat is transferred from the hydrogenation product stream in step b) to another part of the process by means of in-process heat exchange; a mixture of cyclohexanone and cyclohexanol obtained by the process; and a chemical plant suitable for continuously preparing mixture of cyclohexanone and cyclohexanol according to the process.

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Patent Owner(s)

Patent OwnerAddress
CAP III B V6129 EL URMOND

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Brands, Roeland Wilhelmus Theodorus Maria Echt, NL 2 4
Daguenet, Corinne Echt, NL 2 4
De, Korte Robert Jan Echt, NL 1 4
Martens, Wilhelmus Rudolf Maria Echt, NL 2 4
Tinge, Johan Thomas Echt, NL 17 58
Verschuren, Iris Echt, NL 3 4

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