Ligands designed to provide highly active catalyst complexes

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United States of America Patent

PATENT NO 9533297
APP PUB NO 20150087795A1
SERIAL NO

14379418

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Abstract

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A series of ligands with site specific electron donating substituents that form a catalyst complex with a transition metal and are suitable for catalysis of atom transfer radical reactions, including ATRP are described. Faster catalysis rates were observed allowing for low catalyst concentrations and linear increases in molecular weight with monomer conversion, and narrow molecular weight distributions. Cyclic voltammetry revealed that increasing the strength and number of conjugated electron donating groups resulted in more stable complexes and larger ATRP equilibrium constants.

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Patent Owner(s)

  • CARNEGIE MELLON UNIVERSITY

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Burdynska, Joanna Pittsburgh, US 30 280
Elsen, Andrea Pittsburgh, US 6 36
Kwak, Yungwan Breinigsville, US 11 48
Matyjaszewski, Krzysztof Pittsburgh, US 91 3732
Schroeder, Kristin Pittsburgh, US 4 16

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